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A11365 Ethyl 4-bromobenzoate, 98+%

CAS Number
5798-75-4
Synonyms
4-Bromobenzoic acid ethyl ester

Stock No. Size Price ($) Quantity Availability
A11365-09 10g 26.20
A11365-18 50g 62.10
A11365-30 250g 266.00
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Ethyl 4-bromobenzoate, 98+%

MDL
MFCD00016329
EINECS
227-347-2

Chemical Properties

Formula
C9H9BrO2
Formula Weight
229.07
Boiling Point
262-264°
Flash Point
>110°(230°F)
Density
1.403
Refractive Index
1.5460
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

Ethyl 4-bromobenzoate undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Chae MJ, et al. Chemoselective Reduction of Esters to Aldehydes by Potassium Diisobutyl-t-butoxyaluminum Hydride (PDBBA). Bull. Korean Chem. Soc. 2007, 28 (12), 2517.

John M. Herbert. Negishi-type coupling of bromoarenes with dimethylzinc. Tetrahedron Letters. 2004, 45 (4), 817-819.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1408
Beilstein
1867129
Harmonized Tariff Code
2916.39
TSCA
Yes

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