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5798-75-4 - Ethyl 4-bromobenzoate, 98+% - 4-Bromobenzoic acid ethyl ester - A11365 - Alfa Aesar

A11365 Ethyl 4-bromobenzoate, 98+%

CAS Number
5798-75-4
Synonyms
4-Bromobenzoic acid ethyl ester

Size Price ($) Quantity Availability
10g 25.24
50g 59.23
250g 252.35
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Ethyl 4-bromobenzoate, 98+%

MDL
MFCD00016329
EINECS
227-347-2

Chemical Properties

Formula
C9H9BrO2
Formula Weight
229.07
Boiling Point
262-264°
Flash Point
>110°(230°F)
Density
1.403
Refractive Index
1.5460
Solubility
Slightly soluble in water.

Applications

Ethyl 4-bromobenzoate undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Chae MJ, et al. Chemoselective Reduction of Esters to Aldehydes by Potassium Diisobutyl-t-butoxyaluminum Hydride (PDBBA). Bull. Korean Chem. Soc. 2007, 28 (12), 2517.

John M. Herbert. Negishi-type coupling of bromoarenes with dimethylzinc. Tetrahedron Letters. 2004, 45 (4), 817-819.

Other References

Merck
14,1408
Beilstein
1867129
Harmonized Tariff Code
2916.39
TSCA
Yes

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