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A11377 4-Chloroanisole, 99%

CAS Number
623-12-1
Synonyms
4-Methoxychlorobenzene

Stock No. Size Price ($) Quantity Availability
A11377-18 50g 51.90
A11377-30 250g 192.00
A11377-0B 1000g 706.00
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4-Chloroanisole, 99%

MDL
MFCD00000616
EINECS
210-772-2

Chemical Properties

Formula
C7H7ClO
Formula Weight
142.59
Melting point
-18°
Boiling Point
198-200°
Flash Point
78°(172°F)
Density
1.170
Refractive Index
1.5350
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

4-Chloroanisole was found to react with Cu (II)-smectite forming a blue clay-organic complex. 4-Chloroanisole was chosen as the main test substrate for the optimisation studies as it is electronically deactivated and thus resistant to oxidative addition and consequently very reluctant to enter a catalytic manifold.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Antonio Monopoli et. al. Glucose as a clean and renewable reductant in the Pd-nanoparticle-catalyzed reductive homocoupling of bromo- and chloroarenes in water. Journal of Organic Chemistry. 2010, 75 (11), 3908-3911 .

Helge Lemmetyinen,; Jan Konijnenberg,,; Jan Cornelisse,; Cyril A.G.O. Varma. Laser spectroscopic study of the nucleophilic photosubstitution of 4-chloroanisole and 4-fluoroanisole in aqueous solutions . Journal of Photochemistry. 1985, 30(3) , 315-338.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302+H312+H332-H315-H319-H335

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1858901
Harmonized Tariff Code
2909.30
TSCA
Yes

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