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623-12-1 - 4-Chloroanisole, 99% - 4-Methoxychlorobenzene - A11377 - Alfa Aesar

A11377 4-Chloroanisole, 99%

CAS Number
623-12-1
Synonyms
4-Methoxychlorobenzene

Size Price ($) Quantity Availability
50g 50.88
250g 165.60
1000g 542.40
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4-Chloroanisole, 99%

MDL
MFCD00000616
EINECS
210-772-2

Chemical Properties

Formula
C7H7ClO
Formula Weight
142.59
Melting point
-18°
Boiling Point
198-200°
Flash Point
78°(172°F)
Density
1.170
Refractive Index
1.5350
Solubility
Insoluble in water.

Applications

4-Chloroanisole was found to react with Cu (II)-smectite forming a blue clay-organic complex. 4-Chloroanisole was chosen as the main test substrate for the optimisation studies as it is electronically deactivated and thus resistant to oxidative addition and consequently very reluctant to enter a catalytic manifold.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Antonio Monopoli et. al. Glucose as a clean and renewable reductant in the Pd-nanoparticle-catalyzed reductive homocoupling of bromo- and chloroarenes in water. Journal of Organic Chemistry. 2010, 75 (11), 3908-3911 .

Helge Lemmetyinen,; Jan Konijnenberg,,; Jan Cornelisse,; Cyril A.G.O. Varma. Laser spectroscopic study of the nucleophilic photosubstitution of 4-chloroanisole and 4-fluoroanisole in aqueous solutions . Journal of Photochemistry. 1985, 30(3) , 315-338.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1858901
Harmonized Tariff Code
2909.30
TSCA
Yes

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