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A11407 Bromobenzene, 99%

CAS Number
108-86-1
Synonyms

Stock No. Size Price ($) Quantity Availability
A11407-36 500g 32.80
A11407-0E 2500g 108.00
A11407-0C 10000g 338.00
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Bromobenzene, 99%

MDL
MFCD00000055
EINECS
203-623-8

Chemical Properties

Formula
C6H5Br
Formula Weight
157.02
Melting point
-31°
Boiling Point
155-156°
Flash Point
51°(123°F)
Density
1.492
Refractive Index
1.5590
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with diethyl ether, alcohol, carbon tetrachloride, chloroform and benzene.

Applications

Bromobenzene is used as solvent in organic synthesis. It is used to prepare the phenylmagnesium bromide, a Grignard reagent, an intermediate in the preparation of benzoic acid by reacting with carbon dioxide. It is a precursor for making phencyclidine. It is useful for the introduction of phenyl group through palladium-catalyzed coupling reactions viz. the Suzuki reaction.

Notes

Store in cool place. Avoid inhalation of vapor or mist. Incompatible with strong oxidizing agents.

Literature References

Man, I. C.; Şoriga, Ş. G.; Pârvulescu, V. Theoretical study of the adsorption of bromobenzene and aniline on Cu2O(1 1 0):CuO and Cu2O(1 1 1):CuO surfaces. Chem. Phys. Lett. 2014, 604, 38-45.

Zhang, X.; Borjian, S.; Baird, M. C. An unusual product distribution from the reaction of Pd(η3-1-PhC3H4)(η5-C5H5) with a deficiency of PPh3 in the presence of bromobenzene. Transition Met. Chem. 2015, 40 (2), 125-129.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H320

Flammable liquid and vapour. Causes skin irritation. Causes eye irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P314-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1406
Beilstein
1236661
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
CY9000000

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