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Bromobenzene is used as solvent in organic synthesis. It is used to prepare the phenylmagnesium bromide, a Grignard reagent, an intermediate in the preparation of benzoic acid by reacting with carbon dioxide. It is a precursor for making phencyclidine. It is useful for the introduction of phenyl group through palladium-catalyzed coupling reactions viz. the Suzuki reaction.
Man, I. C.; Şoriga, Ş. G.; Pârvulescu, V. Theoretical study of the adsorption of bromobenzene and aniline on Cu2O(1 1 0):CuO and Cu2O(1 1 1):CuO surfaces. Chem. Phys. Lett. 2014, 604, 38-45.
Zhang, X.; Borjian, S.; Baird, M. C. An unusual product distribution from the reaction of Pd(η3-1-PhC3H4)(η5-C5H5) with a deficiency of PPh3 in the presence of bromobenzene. Transition Met. Chem. 2015, 40 (2), 125-129.
Hazard Statements: H226-H315-H320
Flammable liquid and vapour. Causes skin irritation. Causes eye irritation.
Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P314-P332+P313-P337+P313-P363-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant