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108-86-1 - Bromobenzene, 99% - A11407 - Alfa Aesar

A11407 Bromobenzene, 99%

CAS Number
108-86-1
Synonyms

Size Price ($) Quantity Availability
500g 30.08
2500g 97.85
10000g 306.94
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Bromobenzene, 99%

MDL
MFCD00000055
EINECS
203-623-8

Chemical Properties

Formula
C6H5Br
Formula Weight
157.02
Melting point
-31°
Boiling Point
155-156°
Flash Point
51°(123°F)
Density
1.492
Refractive Index
1.5590
Solubility
Miscible with diethyl ether, alcohol, carbon tetrachloride, chloroform and benzene.

Applications

Bromobenzene is used as solvent in organic synthesis. It is used to prepare the phenylmagnesium bromide, a Grignard reagent, an intermediate in the preparation of benzoic acid by reacting with carbon dioxide. It is a precursor for making phencyclidine. It is useful for the introduction of phenyl group through palladium-catalyzed coupling reactions viz. the Suzuki reaction.

Notes

Store in cool place. Avoid inhalation of vapor or mist. Incompatible with strong oxidizing agents.

Literature References

Man, I. C.; Şoriga, Ş. G.; Pârvulescu, V. Theoretical study of the adsorption of bromobenzene and aniline on Cu2O(1 1 0):CuO and Cu2O(1 1 1):CuO surfaces. Chem. Phys. Lett. 2014, 604, 38-45.

Zhang, X.; Borjian, S.; Baird, M. C. An unusual product distribution from the reaction of Pd(η3-1-PhC3H4)(η5-C5H5) with a deficiency of PPh3 in the presence of bromobenzene. Transition Met. Chem. 2015, 40 (2), 125-129.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H303-H411

Flammable liquid and vapour. Causes skin irritation. May be harmful if swallowed. Toxic to aquatic life with long lasting effects.

Precautionary Statements: P210-P273-P280-P240-P241-P303+P361+P353-P362-P312-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,1406
Beilstein
1236661
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
CY9000000

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