The reaction of (pentafluorophenyl)diphenylphosphine with C-ethoxycarbonyl-(p-methoxyphenyl) nitrile imine was used to synthesize [2,3,4,5-tetrafluoro-6-(p- methoxyphenylamino)phenyl]diphenylphosphine oxide whose reduction with trichlorosilane. the reactions of (pentafluorophenyl)diphenylphosphine and bis(penta- fluorophenyl)(phenyl)phosphine with nitrilimines (Housgen 1,3-dipoles) involves two-stage cycloaddi- tion and leads to formation of sufficiently stable fluorophosphoranes.
O. bin Shawkataly,; M.-L. Chong,; H.-K. Fun and K. Sivakumar. (Pentafluorophenyl)diphenylphosphine. Acta Cryst.1999, C52 issue ,1725-1727.
Yu. G. Trishin,; V. I. Namestnikov. Reaction of (Pentafluorophenyl)diphenylphosphine with Azadicarboxylic Acid Dimorpholide . Russian Journal of General Chemistry. 2003, 73(9),1491-1492.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a