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A11428 5-Nitro-1,10-phenanthroline, 98%

CAS Number
4199-88-6
Synonyms

Stock No. Size Price ($) Quantity Availability
A11428-03 1g 79.10
A11428-06 5g 287.00
A11428-14 25g 1273.00
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5-Nitro-1,10-phenanthroline, 98%

MDL
MFCD00004981
EINECS
224-097-6

Chemical Properties

Formula
C12H7N3O2
Formula Weight
225.21
Melting point
202-204°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in ethanol. Insoluble in water.

Applications

5-Nitro-1,10-phenanthroline complexes of iron find wide applications in redox titrations. It is used as a precursor for the synthesis of 5-amino-1,10-phenanthroline, 5-isothiocyanato-1,10-phenanthroline.

Notes

Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

Redox indicator; reagent for rare earth metals.

/n

Ramanavicius, A.; Minkstimiene, A. K.; Vilkonciene, I. M.; Genys, P.; Mikhailova, R.; Semashko, T.; Voronovic, J.; Ramanaviciene, A. Biofuel cell based on glucose oxidase from Penicillium funiculosum 46.1 and horseradish peroxidase. Chem. Eng. J. 2015, 264, 165-173.

Ramos, P. M.; Silva, P. S. P.; Lavin, V.; Martin, I. R.; Lahoz, F.; Posada, P. C.; Silva, M. R.; Gil, J. M. Structure and NIR-luminescence of ytterbium(III) beta-diketonate complexes with 5-nitro-1,10-phenanthroline ancillary ligand: assessment of chain length and fluorination impact. Dalton Trans. 2013, 42 (37), 13516-13526.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332-H335

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
196245
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2933.99
TSCA
Yes

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