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4199-88-6 - 5-Nitro-1,10-phenanthroline, 98% - A11428 - Alfa Aesar

A11428 5-Nitro-1,10-phenanthroline, 98%

CAS Number
4199-88-6
Synonyms

Size Price ($) Quantity Availability
1g 76.84
5g 243.90
25g 1236.00
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5-Nitro-1,10-phenanthroline, 98%

MDL
MFCD00004981
EINECS
224-097-6

Chemical Properties

Formula
C12H7N3O2
Formula Weight
225.21
Melting point
202-204°
Solubility
Soluble in ethanol. Insoluble in water.

Applications

5-Nitro-1,10-phenanthroline complexes of iron find wide applications in redox titrations. It is used as a precursor for the synthesis of 5-amino-1,10-phenanthroline, 5-isothiocyanato-1,10-phenanthroline.

Notes

Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

Redox indicator; reagent for rare earth metals.

/n

Ramanavicius, A.; Minkstimiene, A. K.; Vilkonciene, I. M.; Genys, P.; Mikhailova, R.; Semashko, T.; Voronovic, J.; Ramanaviciene, A. Biofuel cell based on glucose oxidase from Penicillium funiculosum 46.1 and horseradish peroxidase. Chem. Eng. J. 2015, 264, 165-173.

Ramos, P. M.; Silva, P. S. P.; Lavin, V.; Martin, I. R.; Lahoz, F.; Posada, P. C.; Silva, M. R.; Gil, J. M. Structure and NIR-luminescence of ytterbium(III) beta-diketonate complexes with 5-nitro-1,10-phenanthroline ancillary ligand: assessment of chain length and fluorination impact. Dalton Trans. 2013, 42 (37), 13516-13526.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
196245
Harmonized Tariff Code
2933.99
TSCA
Yes

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