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455-14-1 - 4-(Trifluoromethyl)aniline, 98+% - 4-Aminobenzotrifluoride - A11478 - Alfa Aesar

A11478 4-(Trifluoromethyl)aniline, 98+%

CAS Number
455-14-1
Synonyms
4-Aminobenzotrifluoride

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4-(Trifluoromethyl)aniline, 98+%

MDL
MFCD00064396
EINECS
207-236-5

Chemical Properties

Formula
C7H6F3N
Formula Weight
161.13
Melting point
5-8°
Boiling Point
82-84°/12mm
Flash Point
86°(186°F)
Density
1.292
Refractive Index
1.4840
Sensitivity
Air Sensitive

Literature References

As with 2-(Trifluoromethyl)­aniline, A15072, the CF3 group promotes ionization of the amino group under basic conditions. Sodamide in liquid ammonia gives 4-aminobenzonitrile: Chem. Pharm. Bull., 23, 636 (1975).

/n

Similarly, the CF3 group is activated towards nucleophiles. For use in the synthesis of 2-(4-aminophenyl)-substituted imidazolines and tetrahydropyrimidines, see: J. Heterocycl. Chem., 27, 803 (1990).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H319-H341-H400-H410-H227

Toxic if swallowed. Causes serious eye irritation. Suspected of causing genetic defects. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Combustible liquid.

Precautionary Statements: P273-P280h-P305+P351+P338-P309-P310-P302+P352-P501a

Avoid release to the environment. Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1564853
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.43
TSCA
Yes
RTECS
XU9260000

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