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A11494 1-Chlorobutane, 99+%

CAS Number
109-69-3
Synonyms
n-Butyl chloride

Stock No. Size Price ($) Quantity Availability
A11494-AE 100ml 20.00
A11494-AP 500ml 27.30
A11494-0F 2500ml 96.10
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1-Chlorobutane, 99+%

MDL
MFCD00001009
EINECS
203-696-6

Chemical Properties

Formula
CH3(CH2)3Cl
Formula Weight
92.57
Melting point
-123°
Boiling Point
77-78°
Flash Point
-12°(10°F)
Density
0.886
Refractive Index
1.4024
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with alcohol and ether. Immiscible with water.

Applications

1-Chlorobutane is used as intermediates and solvents. It is used for HPLC, spectrophotometry and environmental testing. It is used as an alkylating reagent in organic and organometallic compound synthesis. It is also employed as an anthelmintic in veterinary medicine.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

The Grignard reagent has been recommended as superior to EtMgBr for the preparation of ethynyl magnesium halides from acetylene. For details, see: Org. Synth. Coll., 8, 606 (1993); for generation and use of the Grignard in the Mn-Cu catalyzed 1,4-addition to an enone, see: Org. Synth. Coll., 9, 328 (1998).

Mututuvari, T. M.; Tran, C. D. Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K. J. Hazard. Mater. 2014, 264, 449-459.

Atanase, L. I.; Bistac, S.; Riess, G. Effect of poly(vinyl alcohol-co-vinyl acetate) copolymer blockiness on the dynamic interfacial tension and dilational viscoelasticity of polymer-anionic surfactant complex at the water-1-chlorobutane interface. Soft matter 2015, 11 (13), 2665-2672.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H304

Highly flammable liquid and vapour. May be fatal if swallowed and enters airways.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P280-P301+P310-P303+P361+P353-P331-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Do NOT induce vomiting. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1560
Beilstein
1730909
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.19
TSCA
Yes
RTECS
EJ6300000

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