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A11599 1-(Phenylsulfonyl)pyrrole, 98%

CAS Number
16851-82-4
Synonyms
1-(Benzenesulfonyl)pyrrole

Stock No. Size Price ($) Quantity Availability
A11599-03 1g 32.30
A11599-06 5g 112.00
A11599-14 25g 422.00
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1-(Phenylsulfonyl)pyrrole, 98%

MDL
MFCD00067739

Chemical Properties

Formula
C10H9NO2S
Formula Weight
207.25
Melting point
87-90°
Storage & Sensitivity
Ambient temperatures.

Literature References

Useful protected pyrrole derivative which undergoes regioselective electrophilic substitution, e.g. Friedel-Crafts acylation, at the 3-position: Tetrahedron Lett., 22, 4899, 4901 (1981); Synthesis, 353 (1985) (review); J. Org. Chem., 48, 3214 (1983). The phenylsulfonyl group is readily cleaved by alkaline hydrolysis. For acylation followed by reduction as a route to 3-alkylpyrroles, see: J. Org. Chem., 64, 3379 (1999). See also 1-(Triisopropyl­silyl)­pyrrole, L13152.

/n

With a Grignard reagent, e.g. i-PrMgCl, transmetallation occurs at the 2-position, allowing access to 2-substituted derivatives by reaction with electrophiles: Org. Lett., 6, 293 (2004).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1619427
Harmonized Tariff Code
2935.90
TSCA
No

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