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A11605 Triphenylsilane, 97%

CAS Number
789-25-3
Synonyms
Triphenylhydrosilane
1,1',1''-Silylidynetrisbenzene

Stock No. Size Price ($) Quantity Availability
A11605-09 10g 31.40
A11605-18 50g 102.00
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Triphenylsilane, 97%

MDL
MFCD00003003
EINECS
212-333-0

Chemical Properties

Formula
(C6H5)3SiH
Formula Weight
260.41
Melting point
42-44°
Boiling Point
159-163°/3mm
Flash Point
76°(169°F)
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in methanol. Decomposes in water.

Applications

Triphenylsilane acts as a reactant or reagent for catalytic hydrogen deuterium exchange reactions of silanes, to be oxidized by carbon nanotube-gold nanohybrids, for hydrolysis by ruthenium complexes, for hydrosilylation to produce enolsilanes, for synthesis of bromosilanes, for ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives. It is used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes.

Notes

Air Sensitive. Incompatible with air and oxidizing agents.

Literature References

George C Fortman; Heiko Jacobsen; Luigi Cavallo; Steven P Nolan. Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(III) complexes. Chemical Communications.2011, 47 (34), 9723-9725.

Jubi John; Edmond Gravel; Agnès Hagège; Haiyan Li; Thierry Gacoin; Eric Doris. Catalytic oxidation of silanes by carbon nanotube-gold nanohybrids. Angewandte Chemie. International edition in English.2011, 50 (33), 7533-7536.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
978182
Harmonized Tariff Code
2931.90
TSCA
Yes

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