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Can behave as a protected, highly-reactive cyanamide equivalent. Reacts with ketones in the presence of CsF, or KCN + 18-crown-6, to give N-cyanoimines. In the presence of TiCl4, quinones give N,N'-dicyanoquinodiimines: Angew. Chem. Int. Ed., 23, 447 (1984); Liebigs Ann. Chem., 142 (1986). Molecules of this type have found use as acceptor molecules in charge transfer complexes: J. Org. Chem., 57, 5726 (1992)./n
Hazard Statements: H226-H302-H315-H319-H335
Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280h-P305+P351+P338
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.