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577-19-5 - 1-Bromo-2-nitrobenzene, 99% - 2-Bromonitrobenzene - 2-Nitrobromobenzene - A11686 - Alfa Aesar

A11686 1-Bromo-2-nitrobenzene, 99%

CAS Number
577-19-5
Synonyms
2-Bromonitrobenzene
2-Nitrobromobenzene

Size Price ($) Quantity Availability
50g 61.49
250g 203.40
1000g 568.80
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1-Bromo-2-nitrobenzene, 99%

MDL
MFCD00007045
EINECS
209-409-0

Chemical Properties

Formula
C6H4BrNO2
Formula Weight
202.01
Melting point
40-44°
Boiling Point
261°
Flash Point
112°(233°F)
Solubility
Insoluble in water.

Applications

1-Bromo-2-nitrobenzene is used in organic synthesis. It also can react with 2-methylamino-benzoic acid to get N-methyl-N-(2-nitro-phenyl)-anthranilic acid. And it is also used in the preparation of 4-methoxy-2?-nitrodiphenyl ether, 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Surajit Some.; Jayanta K. Ray.; Martin G. Banwell.; Matthew T. Jones. Fein. New protocols for the synthesis of 3,4-annulated and 4-substituted quinolines from β-bromo-α,β-unsaturated aldehydes and 1-bromo-2-nitrobenzene or 2-bromoacetanilide. Tetrahedron Letters. 2007, 48, (20), 3609-3612.

GHS Hazard and Precautionary Statements

Hazard Statements: H331-H302-H312-H315-H319-H335-H373

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P261-P280-P305+P351+P338-P304+P340-P311-P362-P301+P312-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2044109
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2904.90
TSCA
Yes
RTECS
CY9040450

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