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A11686 1-Bromo-2-nitrobenzene, 99%

CAS Number
577-19-5
Synonyms
2-Bromonitrobenzene
2-Nitrobromobenzene

Stock No. Size Price ($) Quantity Availability
A11686-18 50g 63.20
A11686-30 250g 238.00
A11686-0B 1000g 740.00
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1-Bromo-2-nitrobenzene, 99%

MDL
MFCD00007045
EINECS
209-409-0

Chemical Properties

Formula
C6H4BrNO2
Formula Weight
202.01
Melting point
40-44°
Boiling Point
261°
Flash Point
112°(233°F)
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

1-Bromo-2-nitrobenzene is used in organic synthesis. It also can react with 2-methylamino-benzoic acid to get N-methyl-N-(2-nitro-phenyl)-anthranilic acid. And it is also used in the preparation of 4-methoxy-2?-nitrodiphenyl ether, 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Surajit Some.; Jayanta K. Ray.; Martin G. Banwell.; Matthew T. Jones. Fein. New protocols for the synthesis of 3,4-annulated and 4-substituted quinolines from β-bromo-α,β-unsaturated aldehydes and 1-bromo-2-nitrobenzene or 2-bromoacetanilide. Tetrahedron Letters. 2007, 48, (20), 3609-3612.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332-H335-H373

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P314-P330-P332+P313-P337+P313-P362-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2044109
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2904.99
TSCA
Yes
RTECS
CY9040450

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