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383-67-5 - Allyl trifluoroacetate, 97% - Trifluoroacetic acid allyl ester - A11690 - Alfa Aesar

A11690 Allyl trifluoroacetate, 97%

CAS Number
383-67-5
Synonyms
Trifluoroacetic acid allyl ester

Size Price ($) Quantity Availability
10g 31.93
50g 102.60
250g 442.00
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Allyl trifluoroacetate, 97%

MDL
MFCD00013567
EINECS
206-853-7

Chemical Properties

Formula
CH2=CHCH2O2CCF3
Formula Weight
154.09
Boiling Point
73-75°
Flash Point
-1°(30°F)
Density
1.183
Refractive Index
1.3360
Solubility
Not miscible or difficult to mix with water.

Applications

Used as nucleophilic ally metal precursor in alkylation reaction that generates homoallylic amines. Also used as chemical reagent and intermediate for pharmaceutical.

Notes

Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

Literature References

Robin E. Grote; and Elizabeth R. Jarvo. Palladium-Catalyzed, One-Pot, Three-Component Synthesis of Homoallylic Amines from Aldehydes, Anisidine, and Allyl Trifluoroacetate. Org. Lett. 2009, 11 (2), 485-488.

Debby de Groot; Janine C. de Wilde; Richard J. van Haaren; Joost N. H. Reek; Paul C. J. Kamer; Piet W. N. M. van Leeuwen; Eva B. Eggeling; Dieter Vogt; Huub Kooijman; Anthony L. Spek and Alexander W. van der Made . Palladium complexes of phosphine functionalised carbosilane dendrimers as catalysts in a continuous flow membrane reactor. Chem. Commun. 1999, (17), 1623-1624.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1766312
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.90
TSCA
No

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