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A11690 Allyl trifluoroacetate, 97%

CAS Number
383-67-5
Synonyms
Trifluoroacetic acid allyl ester

Stock No. Size Price ($) Quantity Availability
A11690-09 10g 31.20
A11690-18 50g 114.00
A11690-30 250g 433.00
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Allyl trifluoroacetate, 97%

MDL
MFCD00013567
EINECS
206-853-7

Chemical Properties

Formula
CH2=CHCH2O2CCF3
Formula Weight
154.09
Boiling Point
73-75°
Flash Point
-1°(30°F)
Density
1.183
Refractive Index
1.3360
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Not miscible or difficult to mix with water.

Applications

Used as nucleophilic ally metal precursor in alkylation reaction that generates homoallylic amines. Also used as chemical reagent and intermediate for pharmaceutical.

Notes

Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

Literature References

Robin E. Grote; and Elizabeth R. Jarvo. Palladium-Catalyzed, One-Pot, Three-Component Synthesis of Homoallylic Amines from Aldehydes, Anisidine, and Allyl Trifluoroacetate. Org. Lett. 2009, 11 (2), 485-488.

Debby de Groot; Janine C. de Wilde; Richard J. van Haaren; Joost N. H. Reek; Paul C. J. Kamer; Piet W. N. M. van Leeuwen; Eva B. Eggeling; Dieter Vogt; Huub Kooijman; Anthony L. Spek and Alexander W. van der Made . Palladium complexes of phosphine functionalised carbosilane dendrimers as catalysts in a continuous flow membrane reactor. Chem. Commun. 1999, (17), 1623-1624.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1766312
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.90
TSCA
No

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