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619-45-4 - Methyl 4-aminobenzoate, 98% - H-4-Abz-OMe - 4-Aminobenzoic acid methyl ester - A11715 - Alfa Aesar

A11715 Methyl 4-aminobenzoate, 98%

CAS Number
619-45-4
Synonyms
H-4-Abz-OMe
4-Aminobenzoic acid methyl ester

Size Price ($) Quantity Availability
25g 52.31
100g 143.17
500g 594.31
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Methyl 4-aminobenzoate, 98%

MDL
MFCD00007891
EINECS
210-598-7

Chemical Properties

Formula
C8H9NO2
Formula Weight
151.17
Melting point
110-114°
Solubility
Soluble in alcohol and ether. Slightly soluble in water.

Applications

Methyl 4-aminobenzoate is used in the synthesis of guanidine alkaloids, (±)-martinelline and (±)-martinellic acid by a protic acid catalyzed hetero Diels-Alder coupling reaction with N-Cbz 2-pyrroline. It is also used in organic synthesis and acts as a dye intermediate. Further, it is used to prepare 4-(2-methyl-4-oxo-4H-quinazolin-3-yl)-benzoic acid methyl ester by reacting with 2-acetylamino-benzoic acid.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

Ramya, A.; Sharma, D.; Natarajan, S.; Reddy, M. Highly luminescent and thermally stable lanthanide coordination polymers designed from 4-(dipyridin-2-yl) aminobenzoate: efficient energy transfer from Tb3+ to Eu3+ in a mixed lanthanide coordination compound. Inorg. Chem. 2012, 51 (16), 8818-8826.

Abel, U.; Schlüter, T.; Schulz, A.; Hambruch, E.; Steeneck, C.; Hornberger, M.; Hoffmann, T.; Perovi?-Ottstadt, S.; Kinzel, O.; Burnet, M. Synthesis and pharmacological validation of a novel series of non-steroidal FXR agonists. Bioorg. Med. Chem. Lett. 2010, 20 (16), 4911-4917.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
775913
Harmonized Tariff Code
2922.49
TSCA
Yes
RTECS
DG2900000

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