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A11716 Diethylamine, 99+%

CAS Number
109-89-7
Synonyms

Stock No. Size Price ($) Quantity Availability
A11716-AE 100ml 19.30
A11716-AP 500ml 21.80
A11716-0F 2500ml 55.20
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Diethylamine, 99+%

MDL
MFCD00009032
EINECS
203-716-3

Chemical Properties

Formula
C4H11N
Formula Weight
73.14
Melting point
-50°
Boiling Point
54-55°
Flash Point
-28°(-18°F)
Density
0.706
Refractive Index
1.3850
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Miscible with water, alcohol, ether, chloroform and carbon terachloride.

Applications

Diethylamine is used as a corrosion inhibitor. It is also used in the production of rubber, resins, dyes and pharmaceuticals.

Literature References

Alkali metal diethylamides, generated with n-BuLi or NaH, have been used for the cleavage of ethers: J. Organomet. Chem., 55, 41 (1973); Synthesis, 638 (1980), and of alkyl aryl sulfides, for which HBr and HI are usually poor: Synthesis, 583 (1982).

In combination with Lithium aluminum hydride, A18116, generates lithium tris(diethylamino)aluminum hydride, which is a useful selective reducing agent, for example: esters to aldehydes: J. Org. Chem., 52, 5486 (1987); amides to aldehydes: Tetrahedron Lett., 32, 6903 (1991).

Wang, N. N.; Zhang, D. L.; Jiang, X. H. Detection of Xeljanz Enantiomers in Diethyl Amine Active Pharmaceutical Ingredients and Tablets. Chirality 2015, 27 (3), 235-238.

Higashino, T.; Soya, T.; Kim, W.; Kim, D.; Osuka, A. A Mobius Aromatic [28]Hexaphyrin Bearing a Diethylamine Group: A Rigid but Smooth Conjugation Circuit. Angew. Chem. Int. Ed. 2015, 54 (18), 5456-5459.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H311-H314-H332-H335

Highly flammable liquid and vapour. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements:

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,3111
Beilstein
605268
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2921.19
TSCA
Yes
RTECS
HZ8750000

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