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A11741 2-Mercaptopyridine, 98%

CAS Number
2637-34-5
Synonyms
2-Pyridinethiol

Stock No. Size Price ($) Quantity Availability
A11741-06 5g 24.60
A11741-14 25g 71.70
A11741-22 100g 218.00
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2-Mercaptopyridine, 98%

MDL
MFCD00006285
EINECS
220-131-9

Chemical Properties

Formula
C5H5NS
Formula Weight
111.17
Melting point
124-130°
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Argon.
Solubility
Slightly soluble in chloroform, methanol and dimethyl sulfoxide.

Applications

Employed as a ligand in metal complexes. It can be used to coat porous media to purify plasmid DNA.

Notes

Air Sensitive, keep the container tightly sealed. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Literature References

David B Cordes; and Lyall R Hanton. Structural invariance in silver(I) coordination networks formed using flexible four-armed thiopyridine ligands. Inorganic Chemistry. 2007, 46 (5), 1634-1644.

Alexey V Chuchuryukin et. al. Hydroxy- and mercaptopyridine pincer platinum and palladium complexes generated by silver-free halide abstraction. Inorganic Chemistry, 2006, 45 (5), 2045-2054.

S-Acyl derivatives react with Grignard reagents in a high-yielding synthesis of ketones: J. Am. Chem. Soc., 95, 4763 (1973):

Titanium enolates of S-acyl derivatives react with imines in a one pot synthesis of ß-lactams: J. Org. Chem., 57, 4155 (1992).

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
105758
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
UT9600000

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