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2637-34-5 - 2-Mercaptopyridine, 98% - 2-Pyridinethiol - A11741 - Alfa Aesar

A11741 2-Mercaptopyridine, 98%

CAS Number
2637-34-5
Synonyms
2-Pyridinethiol

Size Price ($) Quantity Availability
5g 18.72
25g 64.80
100g 174.40
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2-Mercaptopyridine, 98%

MDL
MFCD00006285
EINECS
220-131-9

Chemical Properties

Formula
C5H5NS
Formula Weight
111.17
Melting point
124-130°
Sensitivity
Air Sensitive
Solubility
Slightly soluble in chloroform, methanol and dimethyl sulfoxide.

Applications

Employed as a ligand in metal complexes. It can be used to coat porous media to purify plasmid DNA.

Notes

Air Sensitive, keep the container tightly sealed. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Literature References

David B Cordes; and Lyall R Hanton. Structural invariance in silver(I) coordination networks formed using flexible four-armed thiopyridine ligands. Inorganic Chemistry. 2007, 46 (5), 1634-1644.

Alexey V Chuchuryukin et. al. Hydroxy- and mercaptopyridine pincer platinum and palladium complexes generated by silver-free halide abstraction. Inorganic Chemistry, 2006, 45 (5), 2045-2054.

S-Acyl derivatives react with Grignard reagents in a high-yielding synthesis of ketones: J. Am. Chem. Soc., 95, 4763 (1973):

Titanium enolates of S-acyl derivatives react with imines in a one pot synthesis of ß-lactams: J. Org. Chem., 57, 4155 (1992).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
105758
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
UT9600000

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