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84-11-7 - 9,10-Phenanthrenequinone, 95% - A11762 - Alfa Aesar

A11762 9,10-Phenanthrenequinone, 95%

CAS Number
84-11-7
Synonyms

Size Price ($) Quantity Availability
5g 20.24
25g 49.75
100g 144.24
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9,10-Phenanthrenequinone, 95%

MDL
MFCD00001163
EINECS
201-515-5

Chemical Properties

Formula
C14H8O2
Formula Weight
208.22
Melting point
207-212°
Boiling Point
>360°
Flash Point
245°(473°F)
Density
1.405
Solubility
Insoluble in water.

Applications

9,10-Phenanthrenequinon may be used for high quality passivation on silicon (100) surfaces. Quinones may serve as substrates for a variety of flavoenzymes, useful fluorescent compound and quinone. Also used in dyes, as a hardener for dental restoration, for the determination of copper by spectrophotometric method, and for organic synthesis.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Avasthi, Sushobhan, et al. Electronic structure and band alignment of 9, 10-phenanthrenequinone passivated silicon surfaces. Surface Science., 2011, 605 (13), 1308-1312.

P L Chesis; D E Levin; M T Smith; L Ernster; B N Ames. Mutagenicity of quinones: pathways of metabolic activation and detoxification. PNAS, 1984, 81 (6), 1696-1700.

Specific, highly sensitive reagent for arginine and arginyl peptides: Biochem. Biophys. Acta, 130, 538 (1966).

Reagent for dehydrogenation, e.g. of thiazolines to thiazoles in high yield: J. Chem. Soc.(C), 1061 (1966). Review: Chem. Rev., 78, 317 (1978).

Like 1,2-Cyclohexanedione, A14401, has been used by Ley's group for protection of trans-1,2-diols as cyclic diacetals. The method is particularly applicable to the carbohydrate field: Synlett, 793 (1996); J. Chem. Soc., Perkin 1, 2023 (1997):

GHS Hazard and Precautionary Statements

Hazard Statements: H400-H319

Very toxic to aquatic life. Causes serious eye irritation.

Precautionary Statements: P273-P280-P264-P305+P351+P338-P337+P313-P391-P501a

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Collect spillage. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,7213
Beilstein
608838
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2914.69
TSCA
Yes
RTECS
SF7875000

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