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5780-36-9 - 2-(Methylthio)thiophene, 97% - 2-(Methylmercapto)thiophene - Methyl 2-thienyl sulfide - A11763 - Alfa Aesar

A11763 2-(Methylthio)thiophene, 97%

CAS Number
5780-36-9
Synonyms
2-(Methylmercapto)thiophene
Methyl 2-thienyl sulfide

Size Price ($) Quantity Availability
1g 59.12
5g 152.00
25g 605.60
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2-(Methylthio)thiophene, 97%

MDL
MFCD00052382

Chemical Properties

Formula
C5H6S2
Formula Weight
130.23
Boiling Point
82-84°/15mm
Refractive Index
1.5960

Applications

2-(Methylthio)thiophene is used as an intermediate in synthetic chemistry. It is also used in the preparation of 2-thiocyanato-thiophene by reaction with cyanogen iodide using sodium methylmercatide as a reagent.

Notes

Incompatible with oxidizing agents.

Literature References

Zhu, D.; Chang, D.; Shi, L. Transition-metal-free cross-coupling of thioethers with aryl(cyano)iodonium triflates: a facile and efficient method for the one-pot synthesis of thiocyanates. Chem. Comm. 2015, 51 (33), 7180-7183.

Yang, C.; Song, H. L.; Chen, F. Response Surface Methodology for Meat-like Odorants from Maillard Reaction with Glutathione I: the Optimization Analysis and the General Pathway Exploration. J. Food Sci. 2012, 77 (9), C966-C974.

GHS Hazard and Precautionary Statements

Hazard Statements: H319-H335

Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P264-P305+P351+P338-P304+P340-P312-P337+P313-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
106272
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2934.99
TSCA
No

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