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A11763 2-(Methylthio)thiophene, 97%

CAS Number
5780-36-9
Synonyms
2-(Methylmercapto)thiophene
Methyl 2-thienyl sulfide

Stock No. Size Price ($) Quantity Availability
A11763-06 5g 186.00
A11763-14 25g 742.00
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2-(Methylthio)thiophene, 97%

MDL
MFCD00052382

Chemical Properties

Formula
C5H6S2
Formula Weight
130.23
Boiling Point
82-84°/15mm
Refractive Index
1.5960
Storage & Sensitivity
Ambient temperatures.

Applications

2-(Methylthio)thiophene is used as an intermediate in synthetic chemistry. It is also used in the preparation of 2-thiocyanato-thiophene by reaction with cyanogen iodide using sodium methylmercatide as a reagent.

Notes

Incompatible with oxidizing agents.

Literature References

Zhu, D.; Chang, D.; Shi, L. Transition-metal-free cross-coupling of thioethers with aryl(cyano)iodonium triflates: a facile and efficient method for the one-pot synthesis of thiocyanates. Chem. Comm. 2015, 51 (33), 7180-7183.

Yang, C.; Song, H. L.; Chen, F. Response Surface Methodology for Meat-like Odorants from Maillard Reaction with Glutathione I: the Optimization Analysis and the General Pathway Exploration. J. Food Sci. 2012, 77 (9), C966-C974.

GHS Hazard and Precautionary Statements

Hazard Statements: H319-H335

Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280i-P304+P340-P305+P351+P338-P312-P337+P313-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
106272
Harmonized Tariff Code
2934.99
TSCA
No

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