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A11766 Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

CAS Number
106-95-6
Synonyms
3-Bromo-1-propene

Stock No. Size Price ($) Quantity Availability
A11766-30 250g 27.10
A11766-0B 1000g 73.50
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Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

MDL
MFCD00000244
EINECS
203-446-6

Chemical Properties

Formula
C3H5Br
Formula Weight
120.98
Melting point
-119°
Boiling Point
70-71°
Flash Point
-2°(28°F)
Density
1.398
Refractive Index
1.4700
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Slightly miscible with water.

Applications

Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.

Notes

Moisture and light sensitive. Incompatible with oxidizing agents, alkali metals, alkaline earth metals, amides, amines and powdered metals.

Literature References

Pandey, G.; Kant, R.; Batra, S. A general route to the synthesis of indoloazocines using allyl bromides prepared from Morita-Baylis-Hillman adducts. Tetrahedron Lett. 2015, 56 (7), 930-933.

Fananas-Mastral, M.; Vitale, R.; Perez, M.; Feringa, B. L. Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Allylic Alkylation of (Z)-Allyl Bromides with Organolithium Reagents. Chem. Eur. J. 2015, 21 (11), 4209-4212.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301-H314-H331-H335-H340-H350

Highly flammable liquid and vapour. Toxic if swallowed. Causes severe skin burns and eye damage. Toxic if inhaled. May cause respiratory irritation. May cause genetic defects. May cause cancer.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,288
Hazard Class
3
Packing Group
I
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
UC7090000

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