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613-91-2 - Acetophenone oxime, 98% - Methyl phenyl ketoxime - A11804 - Alfa Aesar

A11804 Acetophenone oxime, 98%

CAS Number
613-91-2
Synonyms
Methyl phenyl ketoxime

Size Price ($) Quantity Availability
10g 30.69
50g 84.00
250g 324.80
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Acetophenone oxime, 98%

MDL
MFCD00013931
EINECS
210-360-2

Chemical Properties

Formula
C8H9NO
Formula Weight
135.16
Melting point
58-60°
Boiling Point
118-120°/20mm
Sensitivity
Air & Moisture Sensitive
Solubility
Slightly soluble in water. Soluble in ethyl alcohol almost transparency.

Applications

Used as a ligand in transition-metal complex catalyst chemistry. Oxime acts as an antioxidant, radical scavenger which find applications in textile, plastic, paint, detergent, and rubber industry.

Notes

Air and Moisture Sensitive. Store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

B. J. Gregory; R. B. Moodie; and K. Schofield. Kinetics and mechanism of the Beckmann rearrangement of acetophenone oximes in sulphuric acid. J. Chem. Soc. B.,1970, 338-346.

J Hes; LA Sternson. The metabolism of acetophenone oxime in rat liver homogenates. Drug Metabolism and Dispositon, 1974, 2 (4), 345-350.

The dianion (n-BuLi) reacts to form heterocycles with electrophiles, e.g. methyl benzoate (or benzonitrile), CO2 or benzophenone: J. Org. Chem., 35, 1806 (1970); J. Chem. Soc. (C), 974 (1971); J. Heterocycl. Chem., 13, 449 (1976), respectively:

GHS Hazard and Precautionary Statements

Hazard Statements: H302

Harmful if swallowed.

Precautionary Statements: P264-P270-P301+P312-P330-P501a

Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1562059
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
AM9654000

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