Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

A11804 Acetophenone oxime, 98%

CAS Number
613-91-2
Synonyms
Methyl phenyl ketoxime

Stock No. Size Price ($) Quantity Availability
A11804-09 10g 32.70
A11804-18 50g 112.00
A11804-30 250g 427.00
Add to Cart Bulk/Specialty Print Quote View Item

Acetophenone oxime, 98%

MDL
MFCD00013931
EINECS
210-360-2

Chemical Properties

Formula
C8H9NO
Formula Weight
135.16
Melting point
58-60°
Boiling Point
118-120°/20mm
Storage & Sensitivity
Store at -20°C. Moisture Sensitive. Air Sensitive. Store under Argon.
Solubility
Slightly soluble in water. Soluble in ethyl alcohol almost transparency.

Applications

Used as a ligand in transition-metal complex catalyst chemistry. Oxime acts as an antioxidant, radical scavenger which find applications in textile, plastic, paint, detergent, and rubber industry.

Notes

Air and Moisture Sensitive. Store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

B. J. Gregory; R. B. Moodie; and K. Schofield. Kinetics and mechanism of the Beckmann rearrangement of acetophenone oximes in sulphuric acid. J. Chem. Soc. B.,1970, 338-346.

J Hes; LA Sternson. The metabolism of acetophenone oxime in rat liver homogenates. Drug Metabolism and Dispositon, 1974, 2 (4), 345-350.

The dianion (n-BuLi) reacts to form heterocycles with electrophiles, e.g. methyl benzoate (or benzonitrile), CO2 or benzophenone: J. Org. Chem., 35, 1806 (1970); J. Chem. Soc. (C), 974 (1971); J. Heterocycl. Chem., 13, 449 (1976), respectively:

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1562059
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
AM9654000

Recommended

  • A10226

    2-(Chloromethyl)pyridine hydrochloride, 98%
  • A10580

    Deoxybenzoin, 97%
  • A12053

    Benzaldoxime, predominantly (E)-isomer, 98%
  • L04207

    2,3-Dimethyl-1,3-butadiene, 98%, stab. with 100ppm BHT
  • L08677

    Pinacolone oxime, 98%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware