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A11822 Allyl iodide, 97%, stab. with copper

CAS Number
556-56-9
Synonyms
3-Iodo-1-propene

Stock No. Size Price ($) Quantity Availability
A11822-18 50g 78.00
A11822-30 250g 347.00
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Allyl iodide, 97%, stab. with copper

MDL
MFCD00001094
EINECS
209-130-4

Chemical Properties

Formula
C3H5I
Formula Weight
167.98
Melting point
-99°
Boiling Point
101-103°
Flash Point
18°(64°F)
Density
1.832
Refractive Index
1.5540
Storage & Sensitivity
Keep Cold. Light Sensitive.
Solubility
Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water.

Applications

Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.

Notes

Store at 4°C. Protect from heat. Store away from oxidizing agents. Incompatible with heat, light, amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Literature References

B. Grzybowska; J. Haber; J. Janas. Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons. Journal of Catalysis.1977, 49 150-163.

Tsuneo Imamoto; Yasuo Hatanaka; Yoshinori Tawarayama; Masataka Yokoyama. Tetrahedron Letters.1981, 49 4987-4988.

Precursor, by reaction with In metal powder, of allylindium reagents which add to alkynes to give 1,4-dienes: J. Org. Chem., 62, 2318 (1997). Allylindiums add to cyclopropenes at the more substituted C atom to give allylcyclopropanes: Tetrahedron Lett., 39, 6317 (1998).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H300-H314-H335

Highly flammable liquid and vapour. Fatal if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,294
Beilstein
1697594
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
UD0450000

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