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556-56-9 - Allyl iodide, 97+%, stab. with copper - 3-Iodo-1-propene - A11822 - Alfa Aesar

A11822 Allyl iodide, 97+%, stab. with copper

CAS Number
556-56-9
Synonyms
3-Iodo-1-propene

Size Price ($) Quantity Availability
50g 70.20
250g 260.00
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Allyl iodide, 97+%, stab. with copper

MDL
MFCD00001094
EINECS
209-130-4

Chemical Properties

Formula
C3H5I
Formula Weight
167.98
Melting point
-99°
Boiling Point
101-103°
Flash Point
18°(64°F)
Density
1.832
Refractive Index
1.5540
Sensitivity
Light Sensitive
Solubility
Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water.

Applications

Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.

Notes

Store at 4°C. Protect from heat. Store away from oxidizing agents. Incompatible with heat, light, amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Literature References

B. Grzybowska; J. Haber; J. Janas. Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons. Journal of Catalysis.1977, 49 150-163.

Tsuneo Imamoto; Yasuo Hatanaka; Yoshinori Tawarayama; Masataka Yokoyama. Tetrahedron Letters.1981, 49 4987-4988.

Precursor, by reaction with In metal powder, of allylindium reagents which add to alkynes to give 1,4-dienes: J. Org. Chem., 62, 2318 (1997). Allylindiums add to cyclopropenes at the more substituted C atom to give allylcyclopropanes: Tetrahedron Lett., 39, 6317 (1998).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,294
Beilstein
1697594
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
UD0450000

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