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A11887 Isopropyl cyanoacetate, 97%

CAS Number
13361-30-3
Synonyms
Cyanoacetic acid isopropyl ester

Stock No. Size Price ($) Quantity Availability
A11887-14 25g 33.70
A11887-22 100g 80.10
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Isopropyl cyanoacetate, 97%

MDL
MFCD00019842
EINECS
236-421-3

Chemical Properties

Formula
NCCH2CO2CH(CH3)2
Formula Weight
127.14
Boiling Point
207°
Flash Point
92°(198°F)
Density
1.013
Refractive Index
1.4150
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

Isopropyl cyanoacetate was used in the synthesis of 3-substituted coumarins by undergoing Knöevenagel reactions with aldehydes and ketones.

Notes

Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

Literature References

Kohei Yamashita; Takanori Tanaka; Masahiko Hayashi. Use of isopropyl alcohol as a solvent in Ti(O-i-Pr)4-catalyzed Knöevenagel reactions. Tetrahedron,2005, 61(33), 7981-7985.

Chan Hyuk Kim; Ki Po Jang; Soo Young Choi; Young Keun Chung; and Eun Lee . A Carbonyl Ylide Cycloaddition Approach to Platensimycin. Angewandte Chemie International Edition,2008, 47(47), 4009-4011.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1756014
Harmonized Tariff Code
2926.90
TSCA
No
RTECS
AG4270000

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