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78-94-4 - Methyl vinyl ketone, tech. 90%, stab. - 3-Buten-2-one - A11910 - Alfa Aesar

A11910 Methyl vinyl ketone, tech. 90%, stab.

CAS Number
78-94-4
Synonyms
3-Buten-2-one

Size Price ($) Quantity Availability
25ml 18.72
100ml 44.10
500ml 175.50
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Methyl vinyl ketone, tech. 90%, stab.

MDL
MFCD00008777
EINECS
201-160-6

Chemical Properties

Formula
C4H6O
Formula Weight
70.09
Melting point
-7°
Boiling Point
32-34°/60mm
Flash Point
-6°(21°F)
Density
0.856
Refractive Index
1.4120

Literature References

For an example of the conjugate addition of aldehydes (Stetter reaction), see: Org. Synth. Coll., 8, 620 (1993); for reaction scheme, see 3-Benzyl-5-(2-hydroxyethyl)-4-methyl­thiazolium chloride, L08750.

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For examples of use as a building block in asymmetric syntheses, see: Org. Synth. Coll., 7, 363 (1990); 9, 610 (1998); for reaction schemes for these, see 2-Methyl­cyclopentane-1,3-dione, A13936, and (S)-(-)-1-Phenyl­ethyl­amine, A12632, respectively.

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GHS Hazard and Precautionary Statements

Hazard Statements: H224-H300-H330-H314-H318

Extremely flammable liquid and vapour. Fatal if swallowed. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,6134
Beilstein
506021
Hazard Class
6.1
Packing Group
I
Harmonized Tariff Code
2914.19
TSCA
Yes
RTECS
EM9800000

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