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32864-38-3 - tert-Butyl ethyl malonate, 95% - Malonic acid tert-butyl ethyl ester - A11927 - Alfa Aesar

A11927 tert-Butyl ethyl malonate, 95%

CAS Number
32864-38-3
Synonyms
Malonic acid tert-butyl ethyl ester

Size Price ($) Quantity Availability
5g 16.66
25g 55.68
100g 157.49
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tert-Butyl ethyl malonate, 95%

MDL
MFCD00009193
EINECS
251-269-8

Chemical Properties

Formula
C9H16O4
Formula Weight
188.22
Boiling Point
98-100°/22mm
Flash Point
87°(188°F)
Density
0.994
Refractive Index
1.4160
Solubility
Miscible with most common solvents. Immiscible with water.

Applications

tert-Butyl ethyl malonate is used in the preparation of polar ester-functionalized aliphatic polysulfone. It is also a useful reagent for organic synthesis.

Notes

Incompatible with strong oxidizing agents.

Literature References

Pellissier, H. Recent Developments in Enantioselective Nickel(II)-Catalyzed Conjugate Additions. Adv. Synth. Catal. 2015, 357 (13), 2745-2780.

Thomas, J. B.; Giddings, A. M.; Olepu, S.; Wiethe, R. W.; Warner, K. R.; Sarret, P.; Longpre, J. M.; Runyon, S. P.; Gilmour, B. P. The amide linker in nonpeptide neurotensin receptor ligands plays a key role in calcium signaling at the neurotensin receptor type 2. Bioorg. Med. Chem. Lett. 2015, 25 (10), 2060-2064.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1776681
Harmonized Tariff Code
2917.19
TSCA
No

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