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14660-52-7 - Ethyl 5-bromovalerate, 98% - 5-Bromovaleric acid ethyl ester - Ethyl 5-bromopentanoate - A11952 - Alfa Aesar

A11952 Ethyl 5-bromovalerate, 98%

CAS Number
14660-52-7
Synonyms
5-Bromovaleric acid ethyl ester
Ethyl 5-bromopentanoate

Size Price ($) Quantity Availability
25g 54.38
100g 150.30
500g 594.65
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Ethyl 5-bromovalerate, 98%

MDL
MFCD00000266
EINECS
238-705-2

Chemical Properties

Formula
C7H13BrO2
Formula Weight
209.09
Boiling Point
227°
Flash Point
103°(217°F)
Density
1.306
Refractive Index
1.4580
Sensitivity
Light Sensitive
Solubility
Not miscible or difficult to mix in water.

Applications

Ethyl 5-bromovalerate is employed in the preparation of S(γ-Carboxypropyl)-DL-homocysteine and S(δ-Carboxybutyl)-DL-homocysteine. It is also used in the preparation of ethyl 5-azidovalerate.

Notes

Light Sensitive. Keep away from oxidizing agents. Store in dark.

Literature References

Zengmin Li.; Tae Seok Seo.; Jingyue Ju. 1,3-Dipolar cycloaddition of azides with electron-deficient alkynes under mild condition in water.Tetrahedron Lett.2004,45(15), 3143-3146.

Fernando Albericio.; Nancy Kneib-Cordonier.; Sara Biancalana.; Lajos Gera.; R. Irene Masada.; Derek Hudson.; George Barany. Preparation and application of the 5-(4-(9-fluorenylmethyloxycarbonyl)aminomethyl-3,5-dimethoxyphenoxy)-valeric acid (PAL) handle for the solid-phase synthesis of C-terminal peptide amides under mild conditions.J. Org. Chem.,1990,55(12), 3730-3743.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319

Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Other References

Beilstein
1752023
Harmonized Tariff Code
2915.90
TSCA
No

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