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Ethyl 5-bromovalerate is employed in the preparation of S(γ-Carboxypropyl)-DL-homocysteine and S(δ-Carboxybutyl)-DL-homocysteine. It is also used in the preparation of ethyl 5-azidovalerate.
Zengmin Li.; Tae Seok Seo.; Jingyue Ju. 1,3-Dipolar cycloaddition of azides with electron-deficient alkynes under mild condition in water.Tetrahedron Lett.2004,45(15), 3143-3146.
Fernando Albericio.; Nancy Kneib-Cordonier.; Sara Biancalana.; Lajos Gera.; R. Irene Masada.; Derek Hudson.; George Barany. Preparation and application of the 5-(4-(9-fluorenylmethyloxycarbonyl)aminomethyl-3,5-dimethoxyphenoxy)-valeric acid (PAL) handle for the solid-phase synthesis of C-terminal peptide amides under mild conditions.J. Org. Chem.,1990,55(12), 3730-3743.
Hazard Statements: H315-H319
Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313
Wear protective gloves and eye/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: