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A11952 Ethyl 5-bromovalerate, 98%

CAS Number
14660-52-7
Synonyms
5-Bromovaleric acid ethyl ester
Ethyl 5-bromopentanoate

Stock No. Size Price ($) Quantity Availability
A11952-14 25g 55.50
A11952-22 100g 176.00
A11952-36 500g 689.00
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Ethyl 5-bromovalerate, 98%

MDL
MFCD00000266
EINECS
238-705-2

Chemical Properties

Formula
C7H13BrO2
Formula Weight
209.09
Boiling Point
227°
Flash Point
103°(217°F)
Density
1.306
Refractive Index
1.4580
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Not miscible or difficult to mix in water.

Applications

Ethyl 5-bromovalerate is employed in the preparation of S(γ-Carboxypropyl)-DL-homocysteine and S(δ-Carboxybutyl)-DL-homocysteine. It is also used in the preparation of ethyl 5-azidovalerate.

Notes

Light Sensitive. Keep away from oxidizing agents. Store in dark.

Literature References

Zengmin Li.; Tae Seok Seo.; Jingyue Ju. 1,3-Dipolar cycloaddition of azides with electron-deficient alkynes under mild condition in water.Tetrahedron Lett.2004,45(15), 3143-3146.

Fernando Albericio.; Nancy Kneib-Cordonier.; Sara Biancalana.; Lajos Gera.; R. Irene Masada.; Derek Hudson.; George Barany. Preparation and application of the 5-(4-(9-fluorenylmethyloxycarbonyl)aminomethyl-3,5-dimethoxyphenoxy)-valeric acid (PAL) handle for the solid-phase synthesis of C-terminal peptide amides under mild conditions.J. Org. Chem.,1990,55(12), 3730-3743.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1752023
Harmonized Tariff Code
2915.90
TSCA
No

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