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6622-76-0 - Methyl tiglate, 98% - Methyl trans-2,3-dimethylacrylate - Methyl (E)-2-methyl-2-butenoic acid - A11964 - Alfa Aesar

A11964 Methyl tiglate, 98%

CAS Number
6622-76-0
Synonyms
Methyl trans-2,3-dimethylacrylate
Methyl (E)-2-methyl-2-butenoic acid

Size Price ($) Quantity Availability
10g 30.69
50g 119.48
250g 471.00
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Methyl tiglate, 98%

MDL
MFCD00016654
EINECS
229-575-8

Chemical Properties

Formula
C6H10O2
Formula Weight
114.15
Boiling Point
138-139°
Flash Point
39°(102°F)
Density
0.950
Refractive Index
1.4370
Solubility
Soluble in alcohol, water 3813 mg/L @ 25°C (est).

Applications

It is employed as a perfuming agent in cosmetics industry.

Notes

Store away from oxidizing agents. Keep the container tightly closed. Store in cool, dry conditions in well ventilated place.

Literature References

Herbert O. House.; Gary H. Rasmusson. Stereoselective. Synthesis of α-Substituted α,β-Unsaturated Esters.J. Org. Chem.,1961,26(11), 4278-4281.

Hirokazu Urabe.; Isao Kuwajima. A cyclopentanone annulation via intramolecular acylation of alkylsilanes.J. Org. Chem.,1984,49(6), 1140-1141.

Lithiation and alkylation with allylic rearrangement with 1-iodo-3-trimethylsilylpropane has been used in a versatile cyclopentanone synthesis: J. Org. Chem., 49, 1140 (1984); Org. Synth. Coll., 8, 486 (1993):

GHS Hazard and Precautionary Statements

Hazard Statements: H226

Flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,9433
Beilstein
1720455
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2916.19
TSCA
Yes
RTECS
EM9254600

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