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A11964 Methyl tiglate, 98%

CAS Number
6622-76-0
Synonyms
Methyl trans-2,3-dimethylacrylate
Methyl (E)-2-methyl-2-butenoic acid

Stock No. Size Price ($) Quantity Availability
A11964-18 50g 121.00
A11964-30 250g 490.00
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Methyl tiglate, 98%

MDL
MFCD00016654
EINECS
229-575-8

Chemical Properties

Formula
C6H10O2
Formula Weight
114.15
Boiling Point
138-139°
Flash Point
39°(102°F)
Density
0.950
Refractive Index
1.4370
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in alcohol, water 3813 mg/L @ 25°C (est).

Applications

It is employed as a perfuming agent in cosmetics industry.

Notes

Store away from oxidizing agents. Keep the container tightly closed. Store in cool, dry conditions in well ventilated place.

Literature References

Herbert O. House.; Gary H. Rasmusson. Stereoselective. Synthesis of α-Substituted α,β-Unsaturated Esters.J. Org. Chem.,1961,26(11), 4278-4281.

Hirokazu Urabe.; Isao Kuwajima. A cyclopentanone annulation via intramolecular acylation of alkylsilanes.J. Org. Chem.,1984,49(6), 1140-1141.

Lithiation and alkylation with allylic rearrangement with 1-iodo-3-trimethylsilylpropane has been used in a versatile cyclopentanone synthesis: J. Org. Chem., 49, 1140 (1984); Org. Synth. Coll., 8, 486 (1993):

GHS Hazard and Precautionary Statements

Hazard Statements: H226

Flammable liquid and vapour.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,9433
Beilstein
1720455
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2916.19
TSCA
Yes
RTECS
EM9254600

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