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Potassium hexafluorophosphate is used to prepare 1-butyl-3-methylimidazolium hexaflurorphospahte and other organic hexafluorophospahte compounds such as alkylaryliodonium hexafluorophopahtes and triarylsulfonium hexafluorophosphates. It is also used in the cationic polymerization reactions as photo initiators. It involves in producing catalyst for peptide coupling reactions.
Kitamura, M.; Kato, S.; Yano, M.; Tashiro, N.; Shiratake, Y.; Sando, M.; Okauchi, T. A reagent for safe and efficient diazo-transfer to primary amines: 2-azido-1,3-dimethylimidazolinium hexafluorophosphate. Org. Biomol. Chem. 2014, 12, 4397-4406.
Yang, X.; Yang, R.; Shi, D.; Wang, S.; Chen, J.; Guo, H. Hydrophobic ionic liquids as novel extractants for gold(I) recovery from alkaline cyanide solutions. J. Chem. Technol. Biotechnol. 2015, 6, 1102-1109.
Hazard Statements: H302-H312-H332-H314-H318
Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.