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A12158 4-Methylmorpholine, 99%

CAS Number
109-02-4
Synonyms
N-Methylmorpholine
NMM

Stock No. Size Price ($) Quantity Availability
A12158-AE 100ml 23.90
A12158-AP 500ml 35.10
A12158-0F 2500ml 138.00
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4-Methylmorpholine, 99%

MDL
MFCD00006175
EINECS
203-640-0

Chemical Properties

Formula
C5H11NO
Formula Weight
101.15
Melting point
-65°
Boiling Point
116-118°
Flash Point
14°(57°F)
Density
0.920
Refractive Index
1.4355
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with water.

Applications

4-Methylmorpholine is used as a solvent for dyes, resins, waxes and pharmaceuticals. It acts as a crosslinker in the preparation of polyurethane foams, elastomers and adhesives. It is used as a precursor to prepare N-methylmorpholine N-oxide and morpholinium cation based ionic liquids. It is utilized as corrosion inhibitors and anti-scaling agents in industries.

Notes

Incompatible with acids, acid chlorides, carbon dioxide and strong oxidizing agents.

Literature References

Widely used base in peptide chemistry, milder than triethylamine. Recommended for the avoidance of racemization in the mixed anhydride method of coupling: J. Am. Chem. Soc., 88, 1338 (1966); 89, 5012 (1967). Also preferred in many cases for the formation of active esters or the neutralization of acid salts. For peptide reagents, see Appendix 6.

/n

Pancotti, A.; Parapini, S.; Agli, M. D.; Gambini, L.; Galli, C.; Sangiovanni, E.; Basilico, N.; Bosisio, E.; Taramelli, D.; Romeo, S. Discovery of oxybisbenzoylamides as a new class of antimalarial agents. Med. Chem. Commun. 2015, 6 (6), 1173-1177.

Leng, C.; Kish, J. D.; Roberts, J. E.; Dwebi, I.; Chon, N.; Liu, Y. Temperature-Dependent Henry’s Law Constants of Atmospheric Amines. J. Phys. Chem. A 2015, 199 (33), 8884-8891.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,6277
Beilstein
102719
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2934.99
TSCA
Yes
RTECS
QE5775000

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