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109-02-4 - 4-Methylmorpholine, 99% - N-Methylmorpholine - NMM - A12158 - Alfa Aesar

A12158 4-Methylmorpholine, 99%

CAS Number
109-02-4
Synonyms
N-Methylmorpholine
NMM

Size Price ($) Quantity Availability
100ml 20.25
500ml 33.38
2500ml 120.60
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4-Methylmorpholine, 99%

MDL
MFCD00006175
EINECS
203-640-0

Chemical Properties

Formula
C5H11NO
Formula Weight
101.15
Melting point
-65°
Boiling Point
116-118°
Flash Point
14°(57°F)
Density
0.920
Refractive Index
1.4355
Solubility
Miscible with water.

Applications

4-Methylmorpholine is used as a solvent for dyes, resins, waxes and pharmaceuticals. It acts as a crosslinker in the preparation of polyurethane foams, elastomers and adhesives. It is used as a precursor to prepare N-methylmorpholine N-oxide and morpholinium cation based ionic liquids. It is utilized as corrosion inhibitors and anti-scaling agents in industries.

Notes

Incompatible with acids, acid chlorides, carbon dioxide and strong oxidizing agents.

Literature References

Widely used base in peptide chemistry, milder than triethylamine. Recommended for the avoidance of racemization in the mixed anhydride method of coupling: J. Am. Chem. Soc., 88, 1338 (1966); 89, 5012 (1967). Also preferred in many cases for the formation of active esters or the neutralization of acid salts. For peptide reagents, see Appendix 6.

/n

Pancotti, A.; Parapini, S.; Agli, M. D.; Gambini, L.; Galli, C.; Sangiovanni, E.; Basilico, N.; Bosisio, E.; Taramelli, D.; Romeo, S. Discovery of oxybisbenzoylamides as a new class of antimalarial agents. Med. Chem. Commun. 2015, 6 (6), 1173-1177.

Leng, C.; Kish, J. D.; Roberts, J. E.; Dwebi, I.; Chon, N.; Liu, Y. Temperature-Dependent Henry’s Law Constants of Atmospheric Amines. J. Phys. Chem. A 2015, 199 (33), 8884-8891.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318-H302-H312-H332

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P210-P260-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,6277
Beilstein
102719
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2934.99
TSCA
Yes
RTECS
QE5775000

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