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4-Methylmorpholine is used as a solvent for dyes, resins, waxes and pharmaceuticals. It acts as a crosslinker in the preparation of polyurethane foams, elastomers and adhesives. It is used as a precursor to prepare N-methylmorpholine N-oxide and morpholinium cation based ionic liquids. It is utilized as corrosion inhibitors and anti-scaling agents in industries.
Widely used base in peptide chemistry, milder than triethylamine. Recommended for the avoidance of racemization in the mixed anhydride method of coupling: J. Am. Chem. Soc., 88, 1338 (1966); 89, 5012 (1967). Also preferred in many cases for the formation of active esters or the neutralization of acid salts. For peptide reagents, see Appendix 6./n
Pancotti, A.; Parapini, S.; Agli, M. D.; Gambini, L.; Galli, C.; Sangiovanni, E.; Basilico, N.; Bosisio, E.; Taramelli, D.; Romeo, S. Discovery of oxybisbenzoylamides as a new class of antimalarial agents. Med. Chem. Commun. 2015, 6 (6), 1173-1177.
Leng, C.; Kish, J. D.; Roberts, J. E.; Dwebi, I.; Chon, N.; Liu, Y. Temperature-Dependent Henrys Law Constants of Atmospheric Amines. J. Phys. Chem. A 2015, 199 (33), 8884-8891.
Hazard Statements: H225-H302-H312-H332-H314-H318
Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.