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A12170 Potassium permanganate, 98%

CAS Number
7722-64-7
Synonyms

Stock No. Size Price ($) Quantity Availability
A12170-36 500g 43.50
A12170-0E 2500g 129.00
A12170-0C 10000g 398.00
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Potassium permanganate, 98%

MDL
MFCD00011364
EINECS
231-760-3

Chemical Properties

Formula
KMnO4
Formula Weight
158.03
Melting point
240° dec.
Density
2.7
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Soluble in water.

Applications

Potassium permanganate is an oxidizing agent, is used in the synthesis of organic compounds like ascorbic acid, chloramphenicol, saccharin, isonicotinic acid and pyrazinoic acid and in pharmaceutical intermediate. It is used to remove ferrous impurities from inorganic chemicals. It is also used in analytical chemistry as a reagent for redox titrations and to determine the kappa number of wood pulp. It is mostly used in water treatment and as a disinfectant. It also shows useful application as a chemiluminescence reagent.

Notes

Light sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong reducing agents, powdered metals, peroxides, zinc, copper, alcohols, hydrogen fluoride and acids.

Literature References

The oxidizing power of permanganate can be varied according to the pH of the reaction medium, the use of co-reagents, phase-transfer catalysis, etc. For a comprehensive review of permanganate oxidations in organic chemistry, with particular emphasis on novel applications, see: Synthesis, 85, (1987).

For phase-transfer oxidation, catalyzed by Tetra-n-butyl­ammonium hydrogen sulfate, A14047, of unfunctionalized benzylic methylenes, or benzylic alcohols to carbonyls, see: Synthesis, 915 (1987). Similar transformations have been carried out in the presence of triethylamine: Synthesis, 293 (1989).

For the use of (1-Hexadecyl)­trimethyl­ammonium bromide, A15235, as a surfactant in permanganate oxidations in micelles, see: Can. J. Chem., 67, 1381 (1989).

Classical permanganate cleavage of olefins is difficult to control, and normally proceeds to the highest possible oxidation level. Adsorption of the reagent on moist alumina has been found to attenuate its activity and allow good yields of aldehydes to be obtained. This would appear to provide a possible alternative to ozonolysis for this conversion: J. Org. Chem., 58, 2918 (1993). For use in the cis-hydroxylation of olefins, see Dicyclohexano-18-crown-6, A15344.

For phase-transfer assisted oxidation of primary amines to azo compounds, see: Bull. Soc. Chim. Belg., 102, 59 (1993).

In combination with CuSO 4, has been used as a reagent for the heterogeneous oxidative cyclization of the primary position of a primary-secondary diol to the lactone: J. Chem. Soc., Chem. Commun., 634 (1988); Org, Synth. Coll., 9, 462 (1998):

In combination with TMS chloride and benzyl triethylammonium chloride, generates a reagent for mild anti dichlorination of alkenes, conversion of epoxides to chlorohydrins, and selective oxidation of sulfides to sulfoxides: Tetrahedron Lett., 38, 2339 (1997).

Adcock, J. L.; Barnett, N. W.; Barrow, C. J.; Francis, P. S. Advances in the use of acidic potassium permanganate as a chemiluminescence reagent: A review. Anal. Chim. Acta 2014, 807, 9-28.

Wu, C.; Zhang, G.; Zhang, P.; Chang, C. C. Disintegration of excess activated sludge with potassium permanganate: feasibility, mechanisms and parameter optimization. Chem. Eng. J. 2014, 240, 420-425.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H302-H314-H335-H373

May intensify fire; oxidizer. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P210-P220-P221-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,7655
Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2841.61
TSCA
Yes
RTECS
SD6475000

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