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N-Benzylbenzamide is a convenient precursor to α-substituted benzyl amines and an indicator for the titration of butyl lithium and other lithium bases.
Sung Jin Cho; Jung Seop Roh; Won Suck Sun; Sung Han Kim; Ki Duk Park. N-Benzylbenzamides: a new class of potent tyrosinase inhibitors. Bioorganic & Medicinal Chemistry Letters. 2006, 16 (10), 2682-2684.
O. V. Petrova; I. A. Ushakov; L. N. Sobenina; A. I. Mikhaleva; B. A. Trofimov. Formation of N-benzylbenzamide from benzyl phenyl ketone oxime in a system C2H2-KOH-DMSO. Key role of acetylene. Russian Journal of Organic Chemistry. 2010, 46 (9), 1416-1417.
Used in the preparation of ɑ-substituted benzylamines by lithiation at the benzylic position and subsequent alkylation and hydrolysis: Tetrahedron Lett., 3 (1978).
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant