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A12204 N-Benzylbenzamide, 99+%

CAS Number
1485-70-7
Synonyms
N-Benzoylbenzylamine

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Bulk/Specialty

N-Benzylbenzamide, 99+%

MDL
MFCD00003070
EINECS
216-063-4

Chemical Properties

Formula
C6H5CONHCH2C6H5
Formula Weight
211.26
Melting point
104-108°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in Acetone (25 mg/ml).

Applications

N-Benzylbenzamide is a convenient precursor to α-substituted benzyl amines and an indicator for the titration of butyl lithium and other lithium bases.

Notes

Store in cool, dry place in a tightly sealed container. Store away from oxidizing agent.

Literature References

Sung Jin Cho; Jung Seop Roh; Won Suck Sun; Sung Han Kim; Ki Duk Park. N-Benzylbenzamides: a new class of potent tyrosinase inhibitors. Bioorganic & Medicinal Chemistry Letters. 2006, 16 (10), 2682-2684.

O. V. Petrova; I. A. Ushakov; L. N. Sobenina; A. I. Mikhaleva; B. A. Trofimov. Formation of N-benzylbenzamide from benzyl phenyl ketone oxime in a system C2H2-KOH-DMSO. Key role of acetylene. Russian Journal of Organic Chemistry. 2010, 46 (9), 1416-1417.

Used in the preparation of ɑ-substituted benzylamines by lithiation at the benzylic position and subsequent alkylation and hydrolysis: Tetrahedron Lett., 3 (1978).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2211315
Harmonized Tariff Code
2924.29
TSCA
No

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