Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

576-83-0 - 2-Bromomesitylene, 99% - 2-Bromo-1,3,5-trimethylbenzene - 2,4,6-Trimethylbromobenzene - A12277 - Alfa Aesar

A12277 2-Bromomesitylene, 99%

CAS Number
576-83-0
Synonyms
2-Bromo-1,3,5-trimethylbenzene
2,4,6-Trimethylbromobenzene

Size Price ($) Quantity Availability
50g 27.19
100g 50.88
250g 106.47
500g 198.00
Add to Cart Add to Quote Request View Item

2-Bromomesitylene, 99%

MDL
MFCD00000073
EINECS
209-405-9

Chemical Properties

Formula
C9H11Br
Formula Weight
199.10
Melting point
Boiling Point
224-226°
Flash Point
96°(204°F)
Density
1.322
Refractive Index
1.5520
Sensitivity
Light Sensitive
Solubility
Insoluble in water(20°C) .

Applications

2-Bromomesitylene is a useful synthetic intermediate, Aromatics, Boron Derivatives, Catalyst. It is an intermediate used to prepare Hydrogen[4-[bis(2,4,6-trimethylphenyl)phosphino]-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate (H714510) which is a frustrated phosphonium borate for metal-free catalytic hydrogenation of imines.

Notes

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with Strong oxidizing agents, excess heat.

Literature References

Donald D Glower et. al.Aortic valve replacement via right minithoracotomy versus median sternotomy: a propensity score analysis. Innovations Technology and Techniques in Cardiothoracic and Vascular Surgery. 2014, 9(2),75-81 .

R. M. Keefer,; A. Ottenberg,; L. J. Andrews.The Kinetics of Bromination of Mesitylene in Acetic Acid . J. Am. Chem. Soc. 1956 , 78 (2) ,255-259.

In the presence of Pd catalysts and a base, aryl bromides can act as oxidizing agents for conversion of alcohols to aldehydes and ketones under mild conditions. While bromobenzene is effective for saturated secondary alcohols: Tetrahedron Lett., 1401 (1979), for unsaturated alcohols, arylation competes and 2-bromomesitylene was found to give superior results: Tetrahedron Lett., 22, 1801 (1981); J. Org. Chem., 48, 1286 (1983). See also: J. Org. Chem., 61, 2918 (1996), for a combined desilylation-oxidation technique.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1907245
Harmonized Tariff Code
2903.99
TSCA
Yes

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware