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58757-38-3 - 6-Chloronicotinoyl chloride, 98% - 6-Chloropyridine-3-carbonyl chloride - A12354 - Alfa Aesar

A12354 6-Chloronicotinoyl chloride, 98%

CAS Number
58757-38-3
Synonyms
6-Chloropyridine-3-carbonyl chloride

Size Price ($) Quantity Availability
5g 75.60
25g 228.00
100g 727.20
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6-Chloronicotinoyl chloride, 98%

MDL
MFCD00051775

Chemical Properties

Formula
C6H3Cl2NO
Formula Weight
176.00
Melting point
48-52°
Boiling Point
84-85°/3mm
Sensitivity
Moisture Sensitive

Literature References

Acylation of dimethyl malonate has been carried out using the combination of triethylamine and magnesium chloride (see Diethyl­ malonate, A15468, and Triethyl­amine, A12646, for discussion), followed by one-pot hydrolysis-decarboxylation of the acylmalonate derivative in wet DMSO, to give 5-acetyl-2-chloropyridine in good yield: Tetrahedron, 48, 9233 (1992).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
115927
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2933.39
TSCA
No

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