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A12402 Ethyl 3-bromopropionate, 99%

CAS Number
539-74-2
Synonyms
3-Bromopropionic acid ethyl ester

Stock No. Size Price ($) Quantity Availability
A12402-14 25g 64.90
A12402-22 100g 182.00
A12402-36 500g 761.00
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Ethyl 3-bromopropionate, 99%

MDL
MFCD00000251
EINECS
208-724-0

Chemical Properties

Formula
BrCH2CH2CO2CH2CH3
Formula Weight
181.03
Boiling Point
67-71°/10mm
Flash Point
79°(174°F)
Density
1.416
Refractive Index
1.4520
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Soluble in water, alcohol, chloroform, benzene.

Applications

Ethyl 3-bromopropionate was used in the preparation of (3?,4?-dimethoxyphenyl)-5-oxopentanoic acid.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, Bases, Reducing agents

Literature References

Berlin KD,; Herd MD. Proc. Novel 2-amino-4-aryl-substituted-and 2-amino-4, 5-disubstituted-thiazoles.Oklahoma Acad. Sci. 1991, 71 29-33

Undergoes a "homo-Reformatsky" coupling with carbonyl compounds leading to -lactones. The homoenolate can be generated with various lanthanide metals, La, Ce, Nd or Sm: J. Org. Chem., 55, 1628 (1990):

Cyclopropanols may be synthesized by reaction of ß-halo esters with Grignard reagents and SmI2: Tetrahedron Lett., 32, 7691 (1991).

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1700933
Harmonized Tariff Code
2915.90
TSCA
Yes

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