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1821-36-9 - N-Cyclohexylaniline, 98% - N-Phenylcyclohexylamine - A12409 - Alfa Aesar

A12409 N-Cyclohexylaniline, 98%

CAS Number
1821-36-9
Synonyms
N-Phenylcyclohexylamine

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N-Cyclohexylaniline, 98%

MDL
MFCD00014284
EINECS
217-344-4

Chemical Properties

Formula
C12H17N
Formula Weight
175.28
Melting point
14-15°
Boiling Point
279°
Flash Point
136°(277°F)
Density
1.0155
Refractive Index
1.560
Solubility
Not miscible or difficult to mix in water.

Applications

N-Cyclohexylaniline is used as reagent in palladium-catalyzed amination of aromatic bromides. It is also used to produce N-cyclohexyl-N-phenyl-urea at ambient temperature.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Mahavir Prashad.; Xiao Yin Mak.; Yugang Liu.; Oljan Repic. Palladium-Catalyzed Amination of Aryl Bromides with Hindered N-Alkyl-Substituted Anilines Using a Palladium(I) Tri-tert-butylphosphine Bromide Dimer. J. Org. Chem. 2003, 68 (3), 1163-1164.

Sunggak Kim.; Chang Ho Oh.; Jae Suk Ko.; Kyo Han Ahn.; Yong Jin Kim. Zinc-modified cyanoborohydride as a selective reducing agent. J. Org. Chem. 1985, 50 (11), 1927-1932.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P301+P310a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF SWALLOWED: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2209864
Harmonized Tariff Code
2921.42
TSCA
Yes

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