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A12432 Chlorodifluoroacetic anhydride, 98+%

CAS Number
2834-23-3
Synonyms

Stock No. Size Price ($) Quantity Availability
A12432-09 10g 50.20
A12432-18 50g 179.00
A12432-30 250g 827.00
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Chlorodifluoroacetic anhydride, 98+%

MDL
MFCD00000774
EINECS
220-603-4

Chemical Properties

Formula
(ClCF2CO)2O
Formula Weight
242.94
Boiling Point
92-93°
Density
1.393
Refractive Index
1.3470
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Slightly Soluble in water. (1.4 g/L) (25°C)

Applications

It is used as the reagent for the derivatization of amines, alcohols, etc., for GC purposes. It has been utilized for dual element acetylation tagging derivatization of amines by using microwave sustained helium emission detector1 and as a derivatization reagent in determination of estrone and 17β-estradiol in hair by GC-MS2.

Notes

Moisture sensitive. Handle under dry protective gas. Keep away from oxidizing agents, strong bases.

Literature References

D.F. Hagen.; J.S. Marhevka.; L.C. Haddad. Multi-element taggant and dual homolog derivatization concepts in GC/MED. Spectrochim. Acta, Part B . 1985, 40 (1-2),335-347.

Donald F. Hagen.; Louis C. Haddad.; John S. Marhevka. Solution and gas phase deuterium derivatization reactions for gas chromatography/microwave emission detection.Spectrochim. Acta, Part B . 1987, 42 (1-2), 253-267.

Reagent for the derivatization of amines, alcohols, etc., for GC purposes.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1912832
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2915.90
TSCA
Yes

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