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610-94-6 - Methyl 2-bromobenzoate, 99% - 2-Bromobenzoic acid methyl ester - A12435 - Alfa Aesar

A12435 Methyl 2-bromobenzoate, 99%

CAS Number
610-94-6
Synonyms
2-Bromobenzoic acid methyl ester

Size Price ($) Quantity Availability
25g 28.43
100g 105.06
500g 456.29
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Methyl 2-bromobenzoate, 99%

MDL
MFCD00016328
EINECS
210-241-5

Chemical Properties

Formula
C8H7BrO2
Formula Weight
215.05
Boiling Point
252°
Flash Point
>110°(230°F)
Density
1.532
Refractive Index
1.5590
Solubility
Insoluble in water.

Applications

Methyl 2-bromobenzoate under Heck reaction with acrylonitrile results in lactonization to give the benzofuran-2-one 3-(cyanomethyl)-2-coumaranone. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals

Notes

Store in a cool place. Keep away from oxidizing agents.

Literature References

Stephan Thorand.; Norbert Krause. Improved Procedures for the Palladium-Catalyzed Coupling of Terminal Alkynes with Aryl Bromides (Sonogashira Coupling). J. Org. Chem. 1998, 63 (23),8551-8553.

Carsten Bolm.; Jens P. Hildebrand. Palladium-catalyzed carbon?nitrogen bond formation: A novel, catalytic approach towards N-arylated sulfoximines. Tetrahedron Lett.. 1998, 39 (32),5731-5734.

Heck reaction with acrylonitrile results in lactonization to give the benzofuran-2-one 3-(cyanomethyl)-2-coumaranone: J. Heterocycl. Chem., 32, 1587 (1995):

Other References

Beilstein
1862501
Harmonized Tariff Code
2916.39
TSCA
Yes

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