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A12460 Diethyl diallylmalonate, 97+%

CAS Number
3195-24-2
Synonyms
Diallylmalonic acid diethyl ester

Stock No. Size Price ($) Quantity Availability
A12460-09 10g 54.80
A12460-18 50g 203.00
A12460-30 250g 799.00
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Diethyl diallylmalonate, 97+%

MDL
MFCD00009126
EINECS
221-696-4

Chemical Properties

Formula
C13H20O4
Formula Weight
240.30
Boiling Point
242-244°
Flash Point
>110°(230°F)
Density
0.993
Refractive Index
1.4460
Storage & Sensitivity
Ambient temperatures.
Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)

Applications

Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Notes

Store under cool dry place. Ensure good ventilation.

Literature References

Piotr Nieczypor.; Wlodzimierz Buchowicz.; Wim J.N Meester.; Floris P.J.T Rutjes.; Johannes C Mol. Synthesis and application of a new polystyrene-supported ruthenium carbene catalyst for alkene metathesis. Tetrahedron Lett.. 2001, 42 (40),7103-7105.

Matthias Scholl.; Sheng Ding.; Choon Woo Lee.; Robert H. Grubbs. Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands.Org. Lett. 1999, 1 (6),953-956.

Starting material for enantioselective synthesis of carbocyclic nucleoside analogues: J. Org. Chem., 61, 7963 (1996).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1790529
Harmonized Tariff Code
2917.19
TSCA
No

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