I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.
Acetyl Bromide is used as an acetylating agent in the synthesis of fine chemicals, agrochemicals and pharmaceuticals. It is also used as an intermediate for dyes. Further, it reacts with alcohols and amines to produce acetate esters and acetamides. In addition to this, it is involved in the synthetic process of the anti-HIV agent.
In the presence of ZnCl2, adds to a wide range of aldehydes, giving ɑ-bromoalkyl acetates: Helv. Chim Acta, 61, 2047, 2059, 2165 (1978); Synthesis, 593 (1978).
In combination with TFA, OH groups can be acetylated selectively in the presence of primary and secondary amines: J. Med. Chem., 16, 630 (1973); 17, 427 (1974); Synthesis, 249 (1975).
Fukushima, R. S.; Kerley, M. S.; Ramos, M. H.; Porter, J. H.; Kallenbach, R. L. Comparison of acetyl bromide lignin with acid detergent lignin and Klason lignin and correlation with in vitro forage degradability. Anim. Feed Sci. Technol. 2015, 201, 25-37.
Grabber, J. H.; Santoro, N.; Foster, C. E.; Elumalai, S.; Ralph, J.; Pan, X. Incorporation of Flavonoid Derivatives or Pentagalloyl Glucose into Lignin Enhances Cell Wall Saccharification Following Mild Alkaline or Acidic Pretreatments. BioEnerg. Res. 2015, 8 (3), 1391-1400.
Hazard Statements: H227-H314
Combustible liquid. Causes severe skin burns and eye damage.
Precautionary Statements: P210-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant