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1159-54-2 - Tris(4-chlorophenyl)phosphine, 97% - A12487 - Alfa Aesar

A12487 Tris(4-chlorophenyl)phosphine, 97%

CAS Number
1159-54-2
Synonyms

Size Price ($) Quantity Availability
1g 54.38
5g 180.93
25g 836.00
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Tris(4-chlorophenyl)phosphine, 97%

MDL
MFCD00013639
EINECS
214-596-7

Chemical Properties

Formula
C18H12Cl3P
Formula Weight
365.63
Melting point
102-103°
Sensitivity
Air Sensitive

Literature References

In a study of the Mitsunobu coupling of phosphonic acids with alcohols in the presence of Diisopropyl­ azodicarboxyl­ate, L10386 to give phosphonate esters, reaction times were greatly reduced by the use of this phosphine in place of the usual triphenylphosphine: J. Org. Chem., 59, 658 (1994).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
751458
Harmonized Tariff Code
2931.90
TSCA
No

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