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A12487 Tris(4-chlorophenyl)phosphine, 97%

CAS Number
1159-54-2
Synonyms

Stock No. Size Price ($) Quantity Availability
A12487-03 1g 53.90
A12487-06 5g 203.00
A12487-14 25g 844.00
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Tris(4-chlorophenyl)phosphine, 97%

MDL
MFCD00013639
EINECS
214-596-7

Chemical Properties

Formula
C18H12Cl3P
Formula Weight
365.63
Melting point
102-103°
Storage & Sensitivity
Store under Argon. Air Sensitive. Ambient temperatures.

Literature References

In a study of the Mitsunobu coupling of phosphonic acids with alcohols in the presence of Diisopropyl­ azodicarboxyl­ate, L10386 to give phosphonate esters, reaction times were greatly reduced by the use of this phosphine in place of the usual triphenylphosphine: J. Org. Chem., 59, 658 (1994).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
751458
Harmonized Tariff Code
2931.39
TSCA
No

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