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A12534 (1-Pentyl)triphenylphosphonium bromide, 98%

CAS Number
21406-61-1
Synonyms
(n-Amyl)triphenylphosphonium bromide

Stock No. Size Price ($) Quantity Availability
A12534-14 25g 37.50
A12534-22 100g 107.00
A12534-36 500g 383.00
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(1-Pentyl)triphenylphosphonium bromide, 98%

MDL
MFCD00031630
EINECS
244-374-5

Chemical Properties

Formula
CH3(CH2)4P(C6H5)3Br
Formula Weight
413.33
Melting point
164-166°
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Partly miscible in water. Soluble in methanol and chloroform.

Applications

It is used as pharmaceutical intermediates.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Literature References

L. A. Sternson.; R. Chandrasakar. Further evidence for nitrenium ion intermediacy in N-phenylhydroxylamine rearrangement to aminophenol. J. Org. Chem. 1984, 48 (22),4295-4297.

Takeshi Sakamoto.; Kimio Okamoto.; Yasuo Kikugawa. Determination of configurations of N-methoxyimidoyl halides via catalytic hydrogenation. Synthesis of pure (E)-aldoximes. J. Org. Chem. 1992, 57 (11),3245-3248.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332-H335

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3580453
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2931.39
TSCA
No

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