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122-04-3 - 4-Nitrobenzoyl chloride, 98% - A12543 - Alfa Aesar

A12543 4-Nitrobenzoyl chloride, 98%

CAS Number
122-04-3
Synonyms

Size Price ($) Quantity Availability
10g 15.39
250g 38.52
1000g 94.45
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4-Nitrobenzoyl chloride, 98%

MDL
MFCD00007345
EINECS
204-517-4

Chemical Properties

Formula
C7H4ClNO3
Formula Weight
185.57
Melting point
71-74°
Boiling Point
155°/15mm
Flash Point
102°(215°F)
Density
1.53
Sensitivity
Moisture Sensitive
Solubility
Soluble in terahydrofuran, dichloromethane, chloroform and pyridine.

Applications

4-Nitrobenzoyl chloride is used in the preparation of polysubstituted furanonaphthoquinoines. It is also involved in Michael addition, Henry reaction, O-alkylation and cycloaddition reactions. Further, it is employed as an intermediate in active pharmaceutical ingredient and dyes.

Notes

Moisture sensitive. Incompatible with water, alcohols, oxidizing agents and strong bases.

Literature References

Reagent for the preparation of crystalline esters.

Chen, W.; Feng, Y.; Zhang, M.; Wu, J.; Zhang, J.; Gao, X.; He, J.; Zhang, J. Homogeneous benzoylation of cellulose in 1-allyl-3-methylimidazolium chloride: Hammett correlation, mechanism and regioselectivity. RSC Adv. 2015, 5 (72), 58536-58542.

Skácel, J.; Budka, J.; Eigner, V.; Lhoták, P. Regioselective Friedel-Crafts acylation of calix[4]arenes. Tetrahedron 2015, 71 (13), 1959-1965.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P280-P303+P361+P353-P305+P351+P338-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Other References

Merck
14,6590
Beilstein
473192
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2916.39
TSCA
Yes
RTECS
DM6651000

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