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2459-05-4 - Ethyl hydrogen fumarate, 97% - Fumaric acid monoethyl ester - Monoethyl fumarate - A12545 - Alfa Aesar

A12545 Ethyl hydrogen fumarate, 97%

CAS Number
2459-05-4
Synonyms
Fumaric acid monoethyl ester
Monoethyl fumarate

Size Price ($) Quantity Availability
25g 41.41
100g 112.27
500g 378.40
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Ethyl hydrogen fumarate, 97%

MDL
MFCD00002699
EINECS
219-544-7

Chemical Properties

Formula
C6H8O4
Formula Weight
144.13
Melting point
64-65°
Solubility
Soluble in water.

Applications

Ethyl hydrogen fumarate was used in the preparation of photo-crosslinkable macromers. It was also used to synthesize Ugi/intramolecular Diels-Alder (IMDA) cycloaddition products.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents and bases.

Literature References

Dirk W.Grijpma; Qingpu Hou; Jan Feijen. Preparation of biodegradable networks by photo-crosslinking lactide, epsilon-caprolactone and trimethylene carbonate-based oligomers functionalized with fumaric acid monoethyl ester. Biomaterials. 2005, 26, (16)2795-2802

 

K.Paulvannan. An atom-economical approach to conformationally constrained tricyclic nitrogen heterocycles via sequential and tandem Ugi/intramolecular Diels-Alder reaction of pyrrole. Journal of Organic Chemistry. 2004, 69, (4)1207-1214

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2917.19
TSCA
No

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