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A12545 Ethyl hydrogen fumarate, 97%

CAS Number
2459-05-4
Synonyms
Fumaric acid monoethyl ester
Monoethyl fumarate

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Bulk/Specialty

Ethyl hydrogen fumarate, 97%

MDL
MFCD00002699
EINECS
219-544-7

Chemical Properties

Formula
C6H8O4
Formula Weight
144.13
Melting point
64-65°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

Ethyl hydrogen fumarate was used in the preparation of photo-crosslinkable macromers. It was also used to synthesize Ugi/intramolecular Diels-Alder (IMDA) cycloaddition products.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents and bases.

Literature References

Dirk W.Grijpma; Qingpu Hou; Jan Feijen. Preparation of biodegradable networks by photo-crosslinking lactide, epsilon-caprolactone and trimethylene carbonate-based oligomers functionalized with fumaric acid monoethyl ester. Biomaterials. 2005, 26, (16)2795-2802

 

K.Paulvannan. An atom-economical approach to conformationally constrained tricyclic nitrogen heterocycles via sequential and tandem Ugi/intramolecular Diels-Alder reaction of pyrrole. Journal of Organic Chemistry. 2004, 69, (4)1207-1214

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2917.19
TSCA
No

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