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2516-33-8 - Cyclopropanemethanol, 98% - Cyclopropyl carbinol - Cyclopropylmethanol - A12567 - Alfa Aesar

A12567 Cyclopropanemethanol, 98%

CAS Number
2516-33-8
Synonyms
Cyclopropyl carbinol
Cyclopropylmethanol

Size Price ($) Quantity Availability
5g 22.90
25g 51.40
100g 135.00
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Cyclopropanemethanol, 98%

MDL
MFCD00001309
EINECS
219-735-5

Chemical Properties

Formula
C4H8O
Formula Weight
72.11
Melting point
<-60°
Boiling Point
123-124°
Flash Point
35°(95°F)
Density
0.904
Refractive Index
1.4330
Solubility
Fully miscible with water.

Applications

Cyclopropanemethanol is used as an organic chemical synthesis intermediate.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents and acid chlorides.

Literature References

Lewis Brewster Young; Walter S.Trahanovsky. Cerium(IV) oxidation of organic compounds. III. Preparation of cyclopropanecarboxaldehyde from cyclopropanemethanol. J. Org. Chem. 1967, 32, (7)2349-2350

 

Yasunari Maeda; Takahiro Nishimura; Sakae Uemura. Vanadium-catalyzed isomerization of cyclopropanemethanols to homoallylic alcohols involving C-C bond cleavage. Chemistry Letters. 2005, 34, (3)380-381

For conversion to cyclobutene by tert-butoxide-induced elimination from cyclobutyl tosylate, see: Org. Synth. Coll., 7, 117 (1990).

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H301-H311-H332-H319-H373

Flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P210-P260-P280-P240-P301+P310a-P303+P361+P353-P305+P351+P338-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF SWALLOWED: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1846846
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2906.19
TSCA
Yes
RTECS
GZ2212250

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