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A12567 Cyclopropanemethanol, 98%

CAS Number
2516-33-8
Synonyms
Cyclopropyl carbinol
Cyclopropylmethanol

Stock No. Size Price ($) Quantity Availability
A12567-06 5g 24.60
A12567-14 25g 54.50
A12567-22 100g 137.00
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Cyclopropanemethanol, 98%

MDL
MFCD00001309
EINECS
219-735-5

Chemical Properties

Formula
C4H8O
Formula Weight
72.11
Melting point
<-60°
Boiling Point
123-124°
Flash Point
35°(95°F)
Density
0.904
Refractive Index
1.4330
Storage & Sensitivity
Ambient temperatures.
Solubility
Fully miscible with water.

Applications

Cyclopropanemethanol is used as an organic chemical synthesis intermediate.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents and acid chlorides.

Literature References

Lewis Brewster Young; Walter S.Trahanovsky. Cerium(IV) oxidation of organic compounds. III. Preparation of cyclopropanecarboxaldehyde from cyclopropanemethanol. J. Org. Chem. 1967, 32, (7)2349-2350

 

Yasunari Maeda; Takahiro Nishimura; Sakae Uemura. Vanadium-catalyzed isomerization of cyclopropanemethanols to homoallylic alcohols involving C-C bond cleavage. Chemistry Letters. 2005, 34, (3)380-381

For conversion to cyclobutene by tert-butoxide-induced elimination from cyclobutyl tosylate, see: Org. Synth. Coll., 7, 117 (1990).

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H314-H335

Flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1846846
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2906.19
TSCA
Yes
RTECS
GZ2212250

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