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615-13-4 - 2-Indanone, 98% - A12574 - Alfa Aesar

A12574 2-Indanone, 98%

CAS Number
615-13-4
Synonyms

Size Price ($) Quantity Availability
5g 44.91
25g 173.04
100g 526.60
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2-Indanone, 98%

MDL
MFCD00003792
EINECS
210-410-3

Chemical Properties

Formula
C9H8O
Formula Weight
132.16
Melting point
52-56°
Boiling Point
218° dec.
Flash Point
100°(212°F)
Sensitivity
Hygroscopic
Solubility
Insoluble in water.

Applications

2-Indanone undergoes TiCl4-Mg mediated coupling with CHBr3 to yield dibromomethyl carbinol. It reacts with 5,5-dimethyl-3-pyrazolidinone to yield 5,5-dimethyl-2-(1H-indenyl-2)-3-pyrazolidinone. On photolysis by 266-nm one-photon excitation yields o-xylylene. It was used as starting reagent in the synthesis of indene-fused porphyrins.

Notes

Hygroscopic. Incompatible with oxidizing agents. Incompatible with oxidizing agents and bases.

Literature References

Timothy D.Lash; Breland E.Smith; Michael J.Melquist; Bradley A.Godfrey. Synthesis of indenoporphyrins, highly modified porphyrins with reduced diatropic characteristics. Journal of Organic Chemistry. 2011, 76, (13)5335-5345

 

Tu-Hsin Yan; Su-Haur Chang; Cheng-Ta Chang; Chia-Kuan Lin; Chien-Yu Liu. Bromoform activation. TiCl4-Mg-promoted CHBr2- and CBr3- transfer to a variety of aldehydes and ketones. Organic Letters. 2013, 15, (22)5802-5805

Other References

Beilstein
636550
Harmonized Tariff Code
2914.39
TSCA
Yes
RTECS
NK7535500

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