Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

86-93-1 - 1-Phenyl-1H-tetrazole-5-thiol, 99% - 5-Mercapto-1-phenyl-1H-tetrazole - A12656 - Alfa Aesar

A12656 1-Phenyl-1H-tetrazole-5-thiol, 99%

CAS Number
86-93-1
Synonyms
5-Mercapto-1-phenyl-1H-tetrazole

Size Price ($) Quantity Availability
25g 34.51
100g 131.84
500g 418.40
Add to Cart Add to Quote Request View Item

1-Phenyl-1H-tetrazole-5-thiol, 99%

MDL
MFCD00003129
EINECS
201-710-5

Chemical Properties

Formula
C7H6N4S
Formula Weight
178.22
Melting point
ca 145° dec.
Flash Point
138°(280°F)
Sensitivity
Air Sensitive
Solubility
Soluble in 5% ethanol, water (partly), acetone, chloroform, and methanol.

Applications

1-Phenyl-1H-tetrazole-5-thiol is an effective inhibitor of aluminum corrosion in 1M HCl solution. 1-Phenyl-1H-tetrazole-5-thiol was used in the synthesis of oxacyclic building blocks via highly stereoselective radical cyclization and olefin metathesis reactions. It was also used in the synthesis of metalated tetradecyl sulfone. It is also used in the spectrophotometric determination of Pt and Bi.

Notes

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from oxidizing agents.

Literature References

R Cea-Olivares.; OJ Sandoval.; G Espinosa-Perez. New organotin(IV) derivatives of 1-phenyl-1H-tetrazole-5-thiol. Crystal and molecular structure of 1?[Bz3SnSCN4Ph], a polymer built through secondary intermolecular Sn?N bonds. Polyhedron. 2008, 13, (19), 2809-2818.

C Ma.; J Sun. Hydrogen bonding and π-π stacking interaction in the coordination of sulfur and nitrogen donor heterocycle to organotin(IV): syntheses and crystal structures of di- and triorganotin(IV) derivatives with 1-(4-hydroxyphenyl)-1H-tetrazole-5-thiol. Polyhedron. 2004, 23, (9), 2809-2818.

In combination with t-butyl isocyanide, promotes the lactonization of long-chain hydroxy acids: Angew. Chem. Int. Ed., 20, 771 (1981).

GHS Hazard and Precautionary Statements

Hazard Statements: H228

Flammable solid.

Precautionary Statements: P210-P280-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

Other References

Beilstein
139068
Hazard Class
4.1
Packing Group
III
Harmonized Tariff Code
2933.99
TSCA
Yes
RTECS
XF7700000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware