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A12660 trans,trans-2,4-Hexadien-1-ol, 98%, stab. with 0.1% alpha-tocopherol

CAS Number
17102-64-6
Synonyms
1-Hydroxy-2,4-hexadiene
Sorbyl alcohol

Stock No. Size Price ($) Quantity Availability
A12660-06 5g 25.30
A12660-14 25g 82.40
A12660-22 100g 285.00
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trans,trans-2,4-Hexadien-1-ol, 98%, stab. with 0.1% alpha-tocopherol

MDL
MFCD00002925
EINECS
241-173-4

Chemical Properties

Formula
C6H10O
Formula Weight
98.15
Melting point
30-31°
Boiling Point
79-80°/12mm
Flash Point
72°(161°F)
Storage & Sensitivity
Air Sensitive. Light Sensitive. Store under Argon. Ambient temperatures.
Solubility
Slightly miscible with water.

Applications

Trans,trans-2,4-Hexadien-1-ol is used in the preparation of trans-2,3-methano-4(Z)-hexenol by reacting with diiodomethane. It is used as a flavor and fragrance agent having pineapple odor.

Notes

Air and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, acid chlorides and acid anhydrides.

Literature References

Glassner, M.; Oehlenschlaeger, K. K.; Welle, A.; Bruns, M.; Barner-Kowollik, C. Polymer surface patterning via Diels-Alder trapping of photo-generated thioaldehydes. Chem. Commun. 2013, 49 (6), 633-635.

Glassner, M.; Delaittre, G.; Kaupp, M.; Blinco, J. P.; Barner-Kowollik, C. (Ultra) Fast Catalyst-Free Macromolecular Conjugation in Aqueous Environment at Ambient Temperature. J. Am. Chem. Soc. 2012, 134 (17), 7274-7277.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H311-H315-H318

Combustible liquid. Harmful if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye damage.

Precautionary Statements: P210-P264b-P270-P280-P301+P312-P302+P352-P305+P351+P338-P310-P312-P330-P332+P313-P361-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1719718
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2905.39
TSCA
Yes
RTECS
MM3325000

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