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30093-99-3 - 4,4-Dimethyl-2-oxazoline, 98% - A12670 - Alfa Aesar

A12670 4,4-Dimethyl-2-oxazoline, 98%

CAS Number
30093-99-3
Synonyms

Size Price ($) Quantity Availability
5g 46.14
25g 179.22
100g 463.20
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4,4-Dimethyl-2-oxazoline, 98%

MDL
MFCD00014507
EINECS
250-045-7

Chemical Properties

Formula
C5H9NO
Formula Weight
99.13
Boiling Point
99-100°
Flash Point
1°(33°F)
Density
0.940
Refractive Index
1.4190
Sensitivity
Moisture Sensitive
Solubility
Hydrolyzes with water.

Applications

4,4-Dimethyl-2-oxazoline is used in the fictionalization of a non-activated carbon-hydrogen bond.

Notes

Moisture Sensitive. Store in cool dry place in tightly closed container. With good ventilation. Store away from oxidizing agent.

Literature References

Sean H. Wiedemann; Robert G. Bergman; and Jonathan A. Ellman. Rhodium-Catalyzed Direct C-H Addition of 4,4-Dimethyl-2-oxazoline to Alkenes. Org. Lett. 2004, 6(10), 1685-1687.

G. Balavoine; J.C. Clinet. Cyclopalladated 2-t-butyl-4,4-dimethyl-2-oxazoline: its preparation, and use in the functionalisation of a non-activated carbon-hydrogen bond. Journal of Organometallic Chemistry. 1990, 390(3), c84-c88.

For reviews of the chemistry of oxazolines, see: Chem. Rev., 71, 483 (1971); Angew. Chem. Int. Ed., 15, 270 (1976); Tetrahedron, 41, 837 (1985); 50, 2297 (1994).

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1209606
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2934.99
TSCA
No
RTECS
RP6798385

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