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A12838 Pyrrole-2-carboxaldehyde, 99%

CAS Number
1003-29-8
Synonyms

Stock No. Size Price ($) Quantity Availability
A12838-09 10g 54.50
A12838-14 25g 129.00
A12838-22 100g 370.00
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Pyrrole-2-carboxaldehyde, 99%

MDL
MFCD00005217
EINECS
213-705-5

Chemical Properties

Formula
C5H5NO
Formula Weight
95.10
Melting point
40-46°
Boiling Point
217-219°
Flash Point
106°(222°F)
Storage & Sensitivity
Keep Cold. Air Sensitive.
Solubility
Soluble in chloroform, dimethyl sulfoxide and methanol. Insoluble in water.

Applications

Pyrrole-2-carboxaldehyde is used as a pharmaceutical intermediate. It undergoes condensation reaction to produce pyrrole-2-carboxaldehyde salicylhydrazone (PCSH). It is used as a key starting material for the preparation of pyrrole -2-carboxylic acid by oxidation reaction. It is also used to prepare 4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY dyes) through condensation with a pyrrole, which is an important probes for biotechnology and other applications.

Notes

Store in cool place. Air sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, strong reducing agents and strong bases.

Literature References

Rawat, P.; Singh, R. N. Eco-friendly synthesis, spectral and computational study of pyrrole-2-carboxaldehyde salicylhydrazone (PCSH) for its application. J. Mol. Struct. 2015, 1100, 105-115.

Otaibi, A. A.; Gordon, C. P.; Gilbert, J.; Sakoff, J. A.; McCluskey, A. The influence of ionic liquids on the Knoevenagel condensation of 1H-pyrrole-2-carbaldehyde with phenyl acetonitriles - cytotoxic 3-substituted-(1H-pyrrol-2-yl)acrylonitriles. RSC Adv. 2015, 4 (38), 19806-19813.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
105745
Harmonized Tariff Code
2933.99
TSCA
Yes

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