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3764-01-0 - 2,4,6-Trichloropyrimidine, 98% - A12842 - Alfa Aesar

A12842 2,4,6-Trichloropyrimidine, 98%

CAS Number
3764-01-0
Synonyms

Size Price ($) Quantity Availability
5g 20.32
25g 57.38
100g 172.00
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2,4,6-Trichloropyrimidine, 98%

MDL
MFCD00006063
EINECS
223-183-0

Chemical Properties

Formula
C4HCl3N2
Formula Weight
183.43
Melting point
21-25°
Boiling Point
213-215°
Flash Point
>110°(230°F)
Density
1.595
Refractive Index
1.5700
Solubility
Insoluble in water.

Applications

It is applied In selective Suzuki coupling with arylboronic acids has been reported to give 6-arylpyrimidines.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Matteo Zanda, et al. Efficient and regioselective 4-amino-de-chlorination of 2,4,6-trichloropyrimidine with N-sodium carbamates.Tetrahedron Letters.,2000,41(11), 1757-1761.

Cristina Zucca, et al. Regioselective solid-phase 4-amino-de-chlorination of 2,4,6-trichloropyrimidine by resin-supported N-potassium carbamates.Tetrahedron Letters.,2001,42(6), 1033-1035.

Selective Suzuki coupling with arylboronic acids has been reported to give 6-arylpyrimidines: J. Heterocycl. Chem., 43, 127 (2006).

GHS Hazard and Precautionary Statements

Hazard Statements: H314

Causes severe skin burns and eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
118284
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2933.59
TSCA
Yes

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