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A12842 2,4,6-Trichloropyrimidine, 98%

CAS Number
3764-01-0
Synonyms

Stock No. Size Price ($) Quantity Availability
A12842-06 5g 22.70
A12842-14 25g 69.80
A12842-22 100g 210.00
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2,4,6-Trichloropyrimidine, 98%

MDL
MFCD00006063
EINECS
223-183-0

Chemical Properties

Formula
C4HCl3N2
Formula Weight
183.43
Melting point
21-25°
Boiling Point
213-215°
Flash Point
>110°(230°F)
Density
1.595
Refractive Index
1.5700
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

It is applied In selective Suzuki coupling with arylboronic acids has been reported to give 6-arylpyrimidines.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Matteo Zanda, et al. Efficient and regioselective 4-amino-de-chlorination of 2,4,6-trichloropyrimidine with N-sodium carbamates.Tetrahedron Letters.,2000,41(11), 1757-1761.

Cristina Zucca, et al. Regioselective solid-phase 4-amino-de-chlorination of 2,4,6-trichloropyrimidine by resin-supported N-potassium carbamates.Tetrahedron Letters.,2001,42(6), 1033-1035.

Selective Suzuki coupling with arylboronic acids has been reported to give 6-arylpyrimidines: J. Heterocycl. Chem., 43, 127 (2006).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
118284
Harmonized Tariff Code
2933.59
TSCA
Yes

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