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A12876 Phenylselenol, 90+%

CAS Number
645-96-5
Synonyms
Benzeneselenol
Selenophenol

Stock No. Size Price ($) Quantity Availability
A12876-03 1g 49.30
A12876-06 5g 168.00
A12876-14 25g 684.00
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Phenylselenol, 90+%

MDL
MFCD00000001
EINECS
211-457-2

Chemical Properties

Formula
C6H6Se
Formula Weight
157.07
Boiling Point
71-72°/18mm
Flash Point
70°(158°F)
Density
1.479
Refractive Index
1.6120
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Not miscible or difficult to mix in water.

Applications

It is applied for reactions of phenylselenol and its anion. Benzeneselenol can used as starting reagent in the synthesis of monoseleno-substituted 1,3-dienes. It may be used in the synthesis of cationic chalcogenolato-bridged diruthenium complexes.

Notes

Air sensitive. Store away from oxidizing agents and air. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Literature References

Nikolay V Orlov et. al. Exclusive selectivity in the one-pot formation of C-C and C-Se bonds involving Ni-catalyzed alkyne hydroselenation: optimization of the synthetic procedure and a mechanistic study.J Org Chem.,2014,79(24), 12111-12121.

R.J. Puddephatt and P.J. Thompson. Some reactions of methylplatinum and methylgold compounds with phenylselenol, diphenylphosphine, diphenylarsine, N-bromosuccinimide and 2-nitrophenylsulphenyl chloride.J. Organomet. Chem.,1976,117(4), 395-403.

For reactions of phenylselenol and its anion, see Diphenyl­ diselenide, A13919.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H301-H331-H373

Combustible liquid. Toxic if swallowed. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P210-P235-P260-P264b-P270-P271-P280-P301+P310-P304+P340-P311-P314-P330-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Get medical advice/attention if you feel unwell. Rinse mouth. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
385715
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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