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75-26-3 - 2-Bromopropane, 99% - Isopropyl bromide - A12944 - Alfa Aesar

A12944 2-Bromopropane, 99%

CAS Number
75-26-3
Synonyms
Isopropyl bromide

Size Price ($) Quantity Availability
250ml 37.26
1000ml 108.90
5000ml 348.80
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2-Bromopropane, 99%

MDL
MFCD00000147
EINECS
200-855-1

Chemical Properties

Formula
C3H7Br
Formula Weight
123.00
Melting point
-89°
Boiling Point
59-60°
Flash Point
19°(66°F)
Density
1.310
Refractive Index
1.4255
Solubility
Miscible with alcohol, benzene, chloroform and ether. Slightly miscible with water and acetone.

Applications

2-Bromopropane serves as an alkylating agent in organic synthesis. It is also used as an intermediate to form alkylated amines and alkylated metallic compounds. Further, it acts as a solvent for industrial cleaning, degreasing, metal processing and finishing, electronics, aerospace and aviation, aerosols, textiles, adhesives and inks. In addition, it is used for introducing the isopropyl functional group in organic synthesis.

Notes

Avoid all possible sources of ignition.Incompatible with strong oxidizing agents and strong bases.

Literature References

Can be used, (K2CO3 in DMF), to protect phenolic OH groups as their isopropyl ethers, more stable than benzyl ethers to Lewis acids: J. Chem. Soc., Perkin 1, 2593 (1979).

Vatsal, A.; Zinjarde, S. S.; Kumar, A. R. Yarrowia lipolytica NCIM 3589, a tropical marine yeast, degrades bromoalkanes by an initial hydrolytic dehalogenation step. Biodegradation 2015, 26 (2), 127-138.

Simonetti, S. O.; Larghi, E. L.; Kaufman, T. S. Alternate and Step-Economic Synthesis of the β-Methylstyrene Chelating Pre-ligand of the Hoveyda-Grubbs’ II Catalyst. Org. Prep. Proced. Int. 2015, 47 (3), 227-231.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H360-H373

Highly flammable liquid and vapour. May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P210-P260-P201-P280-P281-P240-P241-P303+P361+P353-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,5210
Beilstein
741852
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
TX4111000

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